Synthesis, Crystal Structure and Photoluminescent Property of Zn(II) Complex Constructed from 1,3-Benzenedicarboxylate and 1,4-Di(1-imidazoly)benzene

被引：2

作者：

Deng Yi-Fang ^{[1
]}

Chen Man-Sheng ^{[1
]}

Zhang Chun-Hua ^{[1
]}

Kuang Dai-Zhi ^{[1
]}

Nie Xue ^{[1
]}

Yang Ying-Qun ^{[1
]}

Li Wei ^{[1
]}

机构：

[1] Hengyang Normal Univ, Coll Hunan Prov, Dept Chem & Mat Sci, Key Lab Funct Organometall Mat, Hengyang 421008, Hunan, Peoples R China

来源：

CHINESE JOURNAL OF INORGANIC CHEMISTRY | 2013年 / 29卷 / 10期

关键词：

hydrothermal synthesis; zinc(II) complex; crystal structure; luminescence property; METAL-ORGANIC FRAMEWORKS; COORDINATION POLYMER;

D O I：

10.3969/j.issn.1001-4861.2013.00.365

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new 2D Zn(II) metal-organic framework, [Zn-2(dib)(1,3-BDC)(2)(H2O)] (1), has been synthesized by the hydrothermal reaction of 1,3-benzenedicarboxylate with ZnSO4 center dot H2O in the presence of 1,4-di(1-imidazoly)benzene (dib=1,4-di(1-imidazoly)benzene, 1,3-H2BDC=1,3-benzenedicarboxylate). The crystal is of monoclinic system, space group P2(1)/n, with a=0.803 67(12) nm, b=1.332 7(2) nm, c=2.372 5(4) nm, beta=97.394(3)degrees, V=2.519 9(7) nm(3), Z=4, F(000)=1 392, R=0.052 0 and wR=0.099 4 (I>2 sigma(I)). The two central zinc(II) ions in the complex locate in a different coordination geometry, one is a distorted tetrahedral and the other is a distorted square-pyramidal coordination geometry, respectively. The dib ligand acts as a bridging ligand, which links the 1D double-chain into 2D layer structure. The net is linked into three-dimensional supramolecular network by O-H center dot center dot center dot O hydrogen bonds. CCDC: 895702.

引用

页码：2195 / 2199

页数：5

共 18 条

[11] Nakamoto K., 1997, Infrared and Raman Spectra of Inorganic and Coordination compounds
[12] Deconstructing the Crystal Structures of Metal-Organic Frameworks and Related Materials into Their Underlying Nets
O'Keeffe, Michael
Yaghi, Omar M.
[J]. CHEMICAL REVIEWS, 2012, 112 (02) : 675 - 702
[13] Solid state coordination chemistry of metal-1,2,4-triazolates and the related metal-4-pyridyltetrazolates
Ouellette, Wayne
Jones, Stephanie
Zubieta, Jon
[J]. CRYSTENGCOMM, 2011, 13 (14): : 4457 - 4485
[14] Sheldrick G. M., 1997, SHELXL 97 PROGRAMM R
[15] Synthesis of Metal-Organic Frameworks (MOFs): Routes to Various MOF Topologies, Morphologies, and Composites
Stock, Norbert
Biswas, Shyam
[J]. CHEMICAL REVIEWS, 2012, 112 (02) : 933 - 969
[16] Photochemistry of peroxo complexes induced by LMCT, MLCT and peroxide IL/LLCT excitation
Vogler, Arnd
Kunkely, Horst
[J]. COORDINATION CHEMISTRY REVIEWS, 2006, 250 (13-14) : 1622 - 1626
[17] Assembly of a three-dimensional polyknotted coordination polymer
Withersby, MA
Blake, AJ
Champness, NR
Cooke, PA
Hubberstey, P
Schröder, M
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (17) : 4044 - 4046
[18] Syntheses, structures, and fluxionality of blue luminescent zinc(II) complexes:: Zn(2,2′,2"-tpa)Cl2, Zn(2,2′,2"-tpa)2(O2CCF3)2, and Zn(2,2′,3"-tpa)4(O2CCF3)2 (tpa = tripyridylamine)
Yang, WY
Schmider, H
Wu, QG
Zhang, YS
Wang, SN
[J]. INORGANIC CHEMISTRY, 2000, 39 (11) : 2397 - 2404

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