Recent Development of Hypercrosslinked Microporous Organic Polymers

被引：392

作者：

Xu, Shujun ^{[1
]}

Luo, Yali ^{[1
]}

Tan, Bien ^{[1
]}

机构：

[1] Huazhong Univ Sci & Technol, Sch Chem & Chem Engn, Wuhan 430074, Peoples R China

来源：

MACROMOLECULAR RAPID COMMUNICATIONS | 2013年 / 34卷 / 06期

基金：

美国国家科学基金会;

关键词：

gas storage; hypercrosslinking; microporous polymers; networks; specific surface area; ULTRAHIGH SURFACE-AREA; HYDROGEN STORAGE; CARBON-DIOXIDE; POTENTIAL ADSORBENTS; NANOPOROUS POLYMERS; GAS SORPTION; PORE-SIZE; POLYSTYRENE; FRAMEWORKS; METHANE;

D O I：

10.1002/marc.201200788

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Hypercrosslinked polymers (HCPs) are currently receiving great interest due to their easy preparation, high chemical and thermal stability, and low cost. Combined with the lightweight properties and high surface areas HCPs can be considered as promising materials for gas storage and separation, catalysis, and heavy metal ions removal in wastewater treatment. This Feature Article summarizes strategies for the preparation of HCPs, comprising the post-crosslinking of Davankov-type resins, direct polycondensation of aromatic chloromethyl (or hydroxymethyl) monomers, and knitting aromatic compound polymers (KAPs). The HCPs applications, such as H2 storage, CO2 capture, and heterogeneous catalysis, are also discussed throughout in the article. Finally, the outlook of this research area is given.

引用

页码：471 / 484

页数：14

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