Integrating NiCo Alloys with Their Oxides as Efficient Bifunctional Cathode Catalysts for Rechargeable Zinc-Air Batteries

被引：395

作者：

Liu, Xien ^{[1
]}

Park, Minjoon ^{[1
]}

Kim, Min Gyu ^{[2
]}

Gupta, Shiva ^{[3
]}

Wu, Gang ^{[3
]}

Cho, Jaephil ^{[1
]}

机构：

[1] Natl Inst Sci & Technol UNIST, Sch Energy & Chem Engn, Dept Energy Engn, Ulsan 689798, South Korea

[2] Pohang Accelerator Lab, Beamline Res Div, Pohang 790784, South Korea

[3] SUNY Buffalo, Dept Chem & Biol Engn, Buffalo, NY 14260 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2015年 / 54卷 / 33期

关键词：

bifunctional electrocatalysts; nickel-cobalt alloy; oxygen evolution reaction; oxygen reduction reaction; zinc-air batteries; ENHANCED ELECTROCHEMICAL PERFORMANCE; OXYGEN REDUCTION; CARBON; NANOPARTICLES; PEROVSKITE; GRAPHENE; ELECTROCATALYSTS; NANOCRYSTALS; FABRICATION; ELECTRODE;

D O I：

10.1002/anie.201503612

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The lack of high-efficient, low-cost, and durable bifunctional electrocatalysts that act simultaneously for the oxygen reduction reaction (ORR) and the oxygen evolution reaction (OER) is currently one of the major obstacles to commercializing the electrical rechargeability of zinc-air batteries. A nanocomposite CoO-NiO-NiCo bifunctional electrocatalyst supported by nitrogen-doped multiwall carbon nanotubes (NCNT/CoO-NiO-NiCo) exhibits excellent activity and stability for the ORR/OER in alkaline media. More importantly, real air cathodes made from the bifunctional NCNT/CoO-NiO-NiCo catalysts further demonstrated superior performance to state-of-the-art Pt/C or Pt/C+IrO2 catalysts in primary and rechargeable zinc-air batteries.

引用

页码：9654 / 9658

页数：5

共 50 条

[21] The Recent Advancement of Graphene-Based Cathode Material for Rechargeable Zinc-Air Batteries [J].

Belete, Abrham Sendek ;

Worku, Ababay Ketema ;

Ayele, Delele Worku ;

Assegie, Addisu Alemayehu ;

Teshager, Minbale Admas .

PROCESSES, 2024, 12 (08)

[22] NCNT grafted perovskite oxide as an active bifunctional electrocatalyst for rechargeable zinc-air battery [J].

Li, Fengjiao ;

Mushtaq, Naveed ;

Su, Tong ;

Cui, Yanhui ;

Huang, Jiajia ;

Sun, Mingjuan ;

Singh, Manish ;

Zhao, Xiaolin ;

Maliutina, Kristina ;

Zhang, Yu ;

He, Chuanxin ;

Yang, Ming ;

Zhu, Bin ;

Fan, Liangdong .

MATERIALS TODAY NANO, 2023, 21

[23] Efficient iron-cobalt oxide bifunctional electrode catalysts in rechargeable high current density zinc-air batteries [J].

Sim, Wei Jian ;

Nguyen, Mai Thanh ;

Huang, Zixuan ;

Kheawhom, Soorathep ;

Wattanakit, Chularat ;

Yonezawa, Tetsu .

NANOSCALE, 2022, 14 (22) :8012-8022

[24] Bifunctional porous Co-doped NiO nanoflowers electrocatalysts for rechargeable zinc-air batteries [J].

Qian, Jinmei ;

Guo, Xiaosong ;

Wang, Tongtong ;

Liu, Peitao ;

Zhang, Hong ;

Gao, Daqiang .

APPLIED CATALYSIS B-ENVIRONMENTAL, 2019, 250 :71-77

[25] Manganese-cobalt mixed oxide film as a bifunctional catalyst for rechargeable zinc-air batteries [J].

Davari, Elaheh ;

Johnson, Aliesha D. ;

Mittal, Akshat ;

Xiong, Ming ;

Ivey, Douglas G. .

ELECTROCHIMICA ACTA, 2016, 211 :735-743

[26] NiCo alloy nanoparticles encapsulated in multi-dimensional N-doped carbon architecture as efficient bifunctional catalyst for rechargeable zinc-air batteries [J].

Deng, Daijie ;

Tian, Yuhui ;

Li, Hongping ;

Xu, Li ;

Qian, Junchao ;

Pang, Jingyu ;

Wang, Boxuan ;

Zhang, Qi ;

Li, Henan .

JOURNAL OF ALLOYS AND COMPOUNDS, 2019, 797 :1041-1049

[27] Bifunctional Single Atom Catalysts for Rechargeable Zinc-Air Batteries: From Dynamic Mechanism to Rational Design [J].

Zhang, Peng ;

Chen, Kuo ;

Li, Jiaye ;

Wang, Minmin ;

Li, Min ;

Liu, Yunqi ;

Pan, Yuan .

ADVANCED MATERIALS, 2023, 35 (35)

[28] Controllable Construction of Bifunctional CoxP@N,P-Doped Carbon Electrocatalysts for Rechargeable Zinc-Air Batteries [J].

Shi, Qing ;

Liu, Qiao ;

Zheng, Yapeng ;

Dong, Yaqian ;

Wang, Lin ;

Liu, Hantao ;

Yang, Weiyou .

ENERGY & ENVIRONMENTAL MATERIALS, 2022, 5 (02) :515-523

[29] A Metal-Free N and P-Codoped Carbon Nanosphere as Bifunctional Electrocatalyst for Rechargeable Zinc-Air Batteries [J].

Li, Ping ;

Jang, Haeseong ;

Zhang, Jian ;

Tian, Mochong ;

Chen, Silong ;

Yuan, Bing ;

Wu, Zexing ;

Liu, Xien ;

Cho, Jaephil .

CHEMELECTROCHEM, 2019, 6 (02) :393-397

[30] Recent advances of transition metal based bifunctional electrocatalysts for rechargeable zinc-air batteries [J].

Wei, Licheng ;

Ang, Edison Huixiang ;

Yang, Yang ;

Qin, Yanlin ;

Zhang, Yufei ;

Ye, Minghui ;

Liu, Qi ;

Li, Cheng Chao .

JOURNAL OF POWER SOURCES, 2020, 477

← 1 2 3 4 5 →