Generation, Characterization, and Reactivity of a CuII-Alkylperoxide/Anilino Radical Complex: Insight into the O-O Bond Cleavage Mechanism

被引：30

作者：

Paria, Sayantan ^{[1
]}

Ohta, Takehiro ^{[2
]}

Morimoto, Yuma ^{[1
]}

Ogura, Takashi ^{[2
]}

Sugimoto, Hideki ^{[1
]}

Fujieda, Nobutaka ^{[1
]}

Goto, Kei ^{[3
]}

Asano, Kaori ^{[4
]}

Suzuki, Takeyuki ^{[4
]}

Itoh, Shinobu ^{[1
]}

机构：

[1] Osaka Univ, Grad Sch Engn, Dept Mat & Life Sci, Div Adv Sci & Biotechnol, Suita, Osaka 5650871, Japan

[2] Univ Hyogo, RSC UH LP Ctr, Grad Sch Life Sci, Picobiol Inst, Sayo, Hyogo 6795148, Japan

[3] Tokyo Inst Technol, Grad Sch Sci & Engn, Dept Chem, Meguro Ku, Tokyo 1528551, Japan

[4] Osaka Univ, ISIR, Comprehens Anal Ctr, Ibaraki, Osaka 5670057, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2015年 / 137卷 / 34期

关键词：

GALACTOSE-OXIDASE; COPPER; ACTIVATION; CATION;

D O I：

10.1021/jacs.5b04104

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of [Cu-I(TIPT(3)tren) (CH3CN)]ClO4 (1) and cumene hydroperoxide (C6H5C-(CH3)(2)OOH, ROOH) at-60 degrees C in CH2Cl2 gave a Cu-II- alkylperoxide/anilino radical complex 2, the formation of which was confirmed by UV vis, resonance Raman, EPR, and CSI-mass spectroscopy. The mechanism of formation of 2, as well as its reactivity, has been explored.

引用

页码：10870 / 10873

页数：4

共 21 条

[1] Spectroscopic and theoretical studies of mononuclear copper(II) alkyl- and hydroperoxo complexes: Electronic structure contributions to reactivity [J].