RGe(I)Ge(I)R Compound (R = PhC(NtBu)2)with a Ge-Ge Single Bond and a Comparison with the Gauche Conformation of Hydrazine

被引：169

作者：

Nagendran, Selvarajan ^{[1
]}

Sen, Sakya S. ^{[1
]}

Roesky, Herbert W. ^{[1
]}

Koley, Debasis ^{[2
]}

Grubmueller, Helmut ^{[2
]}

Pal, Aritra ^{[1
]}

Herbst-Irmer, Regine ^{[1
]}

机构：

[1] Univ Gottingen, Inst Anorgan Chem, D-37077 Gottingen, Germany

[2] Max Planck Inst Gottingen, Theoret & Computergestutzte Biophys, D-37077 Gottingen, Germany

来源：

ORGANOMETALLICS | 2008年 / 27卷 / 21期

关键词：

D O I：

10.1021/om800714f

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

This article reports the reduction of the chloride [PhC(NtBu)(2)]GeCl with potassium in THF to afford the reddish crystals of [PhC(NtBu)(2)](2)Ge-2 (2). The molecule of 2 contains a Ge-Ge bond. The X-ray structure and DFT calculation indicate that the Ge-Ge bond possesses an unusual gauche-bent geometry. The Ge-Ge bond length in 2 is 2.570 angstrom, which is very close to the single Ge-Ge interaction (2.61 angstrom) but significantly longer than that for typical digermenes, R2GeGeR2 (2.21-2.51 angstrom) and the two structurally characterized digermynes (2.2850 angstrom and 2.2060 angstrom), which proves that there is no multiple bond character in 2.

引用

页码：5459 / 5463

页数：5

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