Synthesis and Photophysical Properties of Conjugated and Nonconjugated Phthalocyanine-Perylenediimide Systems

被引：11
作者：
Follana-Berna, Jorge [1 ]
Inan, Damla [2 ]
Blas-Ferrando, Vicente M. [1 ]
Gorczak, Natalie [2 ]
Ortiz, Javier [1 ]
Manjon, Felix [1 ]
Fernandez-Lazaro, Fernando [1 ]
Grozema, Ferdinand C. [2 ]
Sastre-Santos, Angela [1 ]
机构：
[1] Univ Miguel Hernandez, Inst Bioingn, Div Quim Organ, Elche 03202, Spain
[2] Delft Univ Technol, Dept Chem Engn, NL-2628 BL Delft, Netherlands
来源：
JOURNAL OF PHYSICAL CHEMISTRY C | 2016年 / 120卷 / 46期
基金：
欧洲研究理事会;
关键词：
ORGANIC SOLAR-CELLS; CHARGE SEPARATION; MAGNESIUM-ION; DYAD; PHOTOSYNTHESIS; COMPLEXATION; TRANSPORT; ACCEPTOR; DYES;
D O I：
10.1021/acs.jpcc.6b07160
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The synthesis and characterization of different conjugated phthalocyanine perylenemonoimidebenzimidazole [ZnPc-PBIm(OR)(4)] and nonconjugated phthalocyanine perylenediimide [ZnPc-PDI(OR)(4)] dyads are carried out. UV-vis, H-1 NMR, and electrochemistry measurements reveal the interaction between perylene and phthalocyanine moieties in the ground state in the conjugated hybrid and the lack of interaction in the nonconjugated one. Ultrafast transient absorption measurements show that a state with substantial charge-transfer character is formed in both compounds, but the rates for the formation and recombination from this state are much faster for the conjugated compound.
引用
收藏
页码：26508 / 26513
页数：6
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