3D WS2 Nanolayers@Heteroatom-Doped Graphene Films as Hydrogen Evolution Catalyst Electrodes

被引：404

作者：

Duan, Jingjing ^{[1
]}

Chen, Sheng ^{[1
]}

Chambers, Benjamin A. ^{[2
]}

Andersson, Gunther G. ^{[2
]}

Qiao, Shi Zhang ^{[1
]}

机构：

[1] Univ Adelaide, Sch Chem Engn, Adelaide, SA 5005, Australia

[2] Flinders Univ S Australia, Sch Chem & Phys Sci, Adelaide, SA 5001, Australia

来源：

ADVANCED MATERIALS | 2015年 / 27卷 / 28期

基金：

澳大利亚研究理事会;

关键词：

2D materials; heteroatom-doped graphene; hydrogen evolution reaction; van der Waals heterostructures; ACTIVE EDGE SITES; MOS2 ULTRATHIN NANOSHEETS; HIGH-PERFORMANCE; TUNGSTEN DISULFIDE; NITROGEN; NANOPARTICLES; ELECTROCATALYSTS; EXFOLIATION; OXIDATION; LAYER;

D O I：

10.1002/adma.201501692

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A 3D catalyst electrode is fabricated by layer-by-layer assembly of 2D WS2 nanolayers and P, N, O-doped graphene sheets into a heterostructured film. The film exhibits remarkable hydrogen evolution performance, benefitting from the utmost exposed active centers on 2D nanolayers, highly expanded surface, and continuous conductive network, as well as strong synergistic effects between the components. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：4234 / 4241

页数：8

共 59 条

[1] Synthesis and Characterization of Hexamethylenediammonium Thiometallates as Precursors of MoS2 and WS2 Catalysts: In situ Activation During HDS of DBT [J].

Alonso-Nunez, G. ;

Huirache-Acuna, R. ;

Paraguay-Delgado, F. ;

Lumbreras, J. A. ;

Garcia-Alamilla, R. ;

Castillo-Mares, A. ;

Romero, R. ;

Somanathan, R. ;

Chianelli, R. R. .

CATALYSIS LETTERS, 2009, 130 (3-4) :318-326

[2] Low Temperature Casting of Graphene with High Compressive Strength [J].

Bi, Hengchang ;

Yin, Kuibo ;

Xie, Xiao ;

Zhou, Yilong ;

Wan, Neng ;

Xu, Feng ;

Banhart, Florian ;

Sun, Litao ;

Ruoff, Rodney S. .

ADVANCED MATERIALS, 2012, 24 (37) :5124-5129

[3] Mechanically strong, electrically conductive, and biocompatible graphene paper [J].

Chen, Haiqun ;

Mueller, Marc B. ;

Gilmore, Kerry J. ;

Wallace, Gordon G. ;

Li, Dan .

ADVANCED MATERIALS, 2008, 20 (18) :3557-+

[4] Facile Fabrication of Nanoparticles Confined in Graphene Films and Their Electrochemical Properties [J].

Chen, Sheng ;

Zhu, Junwu ;

Qiu, Ling ;

Li, Dan ;

Wang, Xin .

CHEMISTRY-A EUROPEAN JOURNAL, 2013, 19 (23) :7631-7636

[5] Ultrathin WS2 Nanoflakes as a High-Performance Electrocatalyst for the Hydrogen Evolution Reaction [J].

Cheng, Liang ;

Huang, Wenjing ;

Gong, Qiufang ;

Liu, Changhai ;

Liu, Zhuang ;

Li, Yanguang ;

Dai, Hongjie .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2014, 53 (30) :7860-7863

[6] Two-Dimensional Nanosheets Produced by Liquid Exfoliation of Layered Materials [J].

Coleman, Jonathan N. ;

Lotya, Mustafa ;

O'Neill, Arlene ;

Bergin, Shane D. ;

King, Paul J. ;

Khan, Umar ;

Young, Karen ;

Gaucher, Alexandre ;

De, Sukanta ;

Smith, Ronan J. ;

Shvets, Igor V. ;

Arora, Sunil K. ;

Stanton, George ;

Kim, Hye-Young ;

Lee, Kangho ;

Kim, Gyu Tae ;

Duesberg, Georg S. ;

Hallam, Toby ;

Boland, John J. ;

Wang, Jing Jing ;

Donegan, John F. ;

Grunlan, Jaime C. ;

Moriarty, Gregory ;

Shmeliov, Aleksey ;

Nicholls, Rebecca J. ;

Perkins, James M. ;

Grieveson, Eleanor M. ;

Theuwissen, Koenraad ;

McComb, David W. ;

Nellist, Peter D. ;

Nicolosi, Valeria .

SCIENCE, 2011, 331 (6017) :568-571

[7] Electronic Transport and Mechanical Properties of Phosphorus- and Phosphorus-Nitrogen-Doped Carbon Nanotubes [J].

Cruz-Silva, Eduardo ;

Lopez-Urias, Florentino ;

Munoz-Sandoval, Emilio ;

Sumpter, Bobby G. ;

Terrones, Humberto ;

Charlier, Jean-Christophe ;

Meunier, Vincent ;

Terrones, Mauricio .

ACS NANO, 2009, 3 (07) :1913-1921

[8] Extraordinary Hydrogen Evolution and Oxidation Reaction Activity from Carbon Nanotubes and Graphitic Carbons [J].

Das, Rajib Kumar ;

Wang, Yan ;

Vasilyeva, Svetlana V. ;

Donoghue, Evan ;

Pucher, Ilaria ;

Kamenov, George ;

Cheng, Hai-Ping ;

Rinzler, Andrew G. .

ACS NANO, 2014, 8 (08) :8447-8456

[9] Porous C3N4 Nanolayers@N-Graphene Films as Catalyst Electrodes for Highly Efficient Hydrogen Evolution [J].

Duan, Jingjing ;

Chen, Sheng ;

Jaroniec, Mietek ;

Qiao, Shi Zhang .

ACS NANO, 2015, 9 (01) :931-940

[10] Shape Control of Mn 3 O 4 Nanoparticles on Nitrogen- Doped Graphene for Enhanced Oxygen Reduction Activity [J].

Duan, Jingjing ;

Chen, Sheng ;

Dai, Sheng ;

Qiao, Shi Zhang .

ADVANCED FUNCTIONAL MATERIALS, 2014, 24 (14) :2072-2078

← 1 2 3 4 5 6 →