Local electrical characterization of cadmium telluride solar cells using low-energy electron beam

被引:35
作者
Yoon, Heayoung P. [1 ,3 ]
Haney, Paul M. [1 ]
Ruzmetov, Dmitry [1 ,3 ]
Xu, Hua [1 ,3 ]
Leite, Marina S. [1 ,3 ]
Hamadani, Behrang H. [2 ]
Talin, A. Alec [1 ]
Zhitenev, Nikolai B. [1 ]
机构
[1] NIST, Ctr Nanoscale Sci & Technol, Gaithersburg, MD 20899 USA
[2] NIST, Div Energy & Environm, Gaithersburg, MD 20899 USA
[3] Univ Maryland, Maryland Nanoctr, College Pk, MD 20742 USA
关键词
EBIC; CdTe; FIB; Grain boundary; Electron beam; Local characterization; MICROSCOPY;
D O I
10.1016/j.solmat.2013.07.024
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
We investigate local electronic properties of cadmium telluride solar cells using electron beam induced current (EBIC) measurements with patterned contacts. EBIC measurements are performed with a spatial resolution as high as approximate to 20 nm both on the top surface and throughout the cross-section of the device, revealing a remarkable degree of electrical inhomogeneity near the p-n junction and enhanced carrier collection in the vicinity of grain boundaries (GB). Simulation results of low energy EBIC suggest that the band bending near a GB is downward, with a magnitude of at least 0.2 eV for the most effective current-collecting GBs. Furthermore, we demonstrate a new approach to investigate local open-circuit voltage by applying an external bias across electrical contact with a point electron-beam injection. The length scale of the nanocontacts is on the length scale of a single or a few grains, confining current path with highly localized photo-generated carriers. (C) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码:499 / 504
页数:6
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