Improved electrochemical properties by lithium insertion into Co3O4 in aqueous LiOH solution

被引:1
|
作者
Liu, Yan [1 ]
Chang, Chengkang [1 ]
Zhang, Dongyun [1 ]
Wu, Ying [1 ]
机构
[1] Shanghai Inst Technol, Sch Mat Sci & Engn, Shanghai 200235, Peoples R China
基金
中国国家自然科学基金;
关键词
Lithium-ion battery; Oxides; Chemical synthesis; Cyclic voltammetry; Electrochemical properties; ION BATTERIES; COBALT OXIDE; THIN-FILMS; ANODE MATERIAL; PERFORMANCE; MICROSPHERES; BEHAVIOR;
D O I
10.1016/j.pnsc.2013.11.010
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
CO3O4 microspheres were synthesized by a simple hydrothermal treatment. The first-cycle charge discharge tests were carried out between 0.6 and 0.6 V vs. SCE. The pristine, discharged and recharged specimens were characterized by X-ray power diffraction and scanning electron microscopy. Cyclic voltammetry (CV) curves of CO3O4 at various concentrations in LiOH solution were investigated. The appearance of the two pairs of redox peaks indicated that two sets of faradaic reactions were involved in the redox reactions of CO3O4 to LiCoO2 and LiHCoO2. (C) 2013 Chinese Materials Research Society. Production and hosting by Etsesicr B.V. Alt rights reserved.
引用
收藏
页码:593 / 597
页数:5
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