Tungsten Oxychloride Compounds Containing [W6O6Cl12]n- (n=2, 3) Clusters

被引：0
|
作者：
Hummel, Thorsten [1 ]
Glaser, Jochen [1 ]
Stroebele, Markus [1 ]
Meyer, H-Juergen [1 ]
机构：
[1] Univ Tubingen, Inst Anorgan Chem, Abt Festkorperchem & Theoret Anorgan Chem, D-72076 Tubingen, Germany
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2013年 / 639卷 / 14期
关键词：
Tungsten oxyhalides; Cluster compounds; Crystal structure; Magnetic properties; CHLORIDE CLUSTERS; ELECTRON-RICH; LUMINESCENCE; MOLYBDENUM(II); HALIDES; W6CL12;
D O I：
10.1002/zaac.201300326
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Three tungsten oxychloride clusters containing the nearly D-3d symmetric [((W6O6Cl6i)-Cl-i)Cl-6(a)](n-) (n = 2, 3) core were prepared from the cluster acid (H5O2)(2)[W6O6Cl12]4H(2)O and structurally characterized by single-crystal X-ray diffraction. The copper compound [Cu(H2O)(4)][W6O6Cl12]12H(2)O releases water molecules to yield [Cu(H2O)(6)][W6O6Cl12]. Both compounds are represented as diamagnetic clusters, having 14 electrons in W-W bonding states. Magnetic measurements on the calcium compound [Ca(H2O)(7)](2)[W6O6Cl12]Cl revealed a paramagnetic cluster having 15 valence electrons.
引用
收藏
页码：2637 / 2642
页数：6
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