Photo-induced dynamic processes in perovskite solar cells: the influence of perovskite composition in the charge extraction and the carrier recombination

被引：0
作者：
Montcada, Nuria F. [1 ]
Mendez, Maria [1 ]
Cho, Kyung Taek [2 ]
Nazeeruddin, Mohammad Khaja [2 ]
Palomares, Emilio [1 ,3 ]
机构：
[1] Barcelona Inst Sci & Technol, Inst Chem Res Catalonia ICIQ, Avda Paisos Catalans 16, E-43007 Tarragona, Spain
[2] Ecole Polytech Fed Lausanne, Inst Chem Sci & Engn, Grp Mol Engn Funct Mat, Rue Ind 17, CH-1951 Sion, Switzerland
[3] ICREA, Passeig Lluis Co 23, E-08010 Barcelona, Spain
来源：
NANOSCALE | 2018年 / 10卷 / 13期
关键词：
METHYLAMMONIUM LEAD IODIDE; ANOMALOUS HYSTERESIS; ION MIGRATION; TRIHALIDE; KINETICS; BEHAVIOR; IMPACT;
D O I：
10.1039/c8nr00180d
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
We describe in this work how the use of the photo-induced charge extraction (PICE) technique can be useful to study and understand the relationship between perovskite composition, ion migration processes and solar cell performance. Our results show that varying the organic cation and halide composition in perovskite crystals has an effect on the charge extraction process, which is related to the differences in the ion migration process occurring during light irradiation. Moreover, we do also observe that different perovskites also show differences in interfacial carrier recombination kinetics under operando conditions but the dynamics are too fast to be influenced by the ion migration.
引用
收藏
页码：6155 / 6158
页数：4
相关论文
共 25 条
  • [11] Parameters Affecting I-V Hysteresis of CH3NH3PbI3 Perovskite Solar Cells: Effects of Perovskite Crystal Size and Mesoporous TiO2 Layer
    Kim, Hui-Seon
    Park, Nam-Gyu
    [J]. JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2014, 5 (17): : 2927 - 2934
  • [12] Perovskite Solar Cells Employing Dopant-Free Organic Hole Transport Materials with Tunable Energy Levels
    Liu, Yongsheng
    Hong, Ziruo
    Chen, Qi
    Chen, Huajun
    Chang, Wei-Hsuan
    Yang, Yang
    Song, Tze-Bin
    Yang, Yang
    [J]. ADVANCED MATERIALS, 2016, 28 (03) : 440 - +
  • [13] Analysis of Photoinduced Carrier Recombination Kinetics in Flat and Mesoporous Lead Perovskite Solar Cells
    Montcada, Nuria F.
    Manuel Marin-Beloqui, Jose
    Cambarau, Werther
    Jimenez-Lopez, Jesus
    Cabau, Lydia
    Cho, Kyung Taek
    Nazeeruddin, Mohammad Khaja
    Palomares, Emilio
    [J]. ACS ENERGY LETTERS, 2017, 2 (01): : 182 - 187
  • [14] Mixed-Organic-Cation Perovskite Photovoltaics for Enhanced Solar-Light Harvesting
    Pellet, Norman
    Gao, Peng
    Gregori, Giuliano
    Yang, Tae-Youl
    Nazeeruddin, Mohammad K.
    Maier, Joachim
    Graetzel, Michael
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2014, 53 (12) : 3151 - 3157
  • [15] Ryan J. W., 2016, ADV ENERGY MATER
  • [16] Cesium-containing triple cation perovskite solar cells: improved stability, reproducibility and high efficiency
    Saliba, Michael
    Matsui, Taisuke
    Seo, Ji-Youn
    Domanski, Konrad
    Correa-Baena, Juan-Pablo
    Nazeeruddin, Mohammad Khaja
    Zakeeruddin, Shaik M.
    Tress, Wolfgang
    Abate, Antonio
    Hagfeldt, Anders
    Gratzel, Michael
    [J]. ENERGY & ENVIRONMENTAL SCIENCE, 2016, 9 (06) : 1989 - 1997
  • [17] Origin and elimination of photocurrent hysteresis by fullerene passivation in CH3NH3PbI3 planar heterojunction solar cells
    Shao, Yuchuan
    Xiao, Zhengguo
    Bi, Cheng
    Yuan, Yongbo
    Huang, Jinsong
    [J]. NATURE COMMUNICATIONS, 2014, 5
  • [18] Low trap-state density and long carrier diffusion in organolead trihalide perovskite single crystals
    Shi, Dong
    Adinolfi, Valerio
    Comin, Riccardo
    Yuan, Mingjian
    Alarousu, Erkki
    Buin, Andrei
    Chen, Yin
    Hoogland, Sjoerd
    Rothenberger, Alexander
    Katsiev, Khabiboulakh
    Losovyj, Yaroslav
    Zhang, Xin
    Dowben, Peter A.
    Mohammed, Omar F.
    Sargent, Edward H.
    Bakr, Osman M.
    [J]. SCIENCE, 2015, 347 (6221) : 519 - 522
  • [19] Anomalous Hysteresis in Perovskite Solar Cells
    Snaith, Henry J.
    Abate, Antonio
    Ball, James M.
    Eperon, Giles E.
    Leijtens, Tomas
    Noel, Nakita K.
    Stranks, Samuel D.
    Wang, Jacob Tse-Wei
    Wojciechowski, Konrad
    Zhang, Wei
    [J]. JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2014, 5 (09): : 1511 - 1515
  • [20] Understanding the rate-dependent J-V hysteresis, slow time component, and aging in CH3NH3PbI3 perovskite solar cells: the role of a compensated electric field
    Tress, W.
    Marinova, N.
    Moehl, T.
    Zakeeruddin, S. M.
    Nazeeruddin, Mohammad Khaja
    Graetzel, M.
    [J]. ENERGY & ENVIRONMENTAL SCIENCE, 2015, 8 (03) : 995 - 1004
123