New homoleptic carbene transfer ligands and related coinage metal complexes

被引：41

作者：

Papini, Grazia ^{[1
]}

Bandoli, Giuliano ^{[2
]}

Dolmella, Alessandro ^{[2
]}

Lobbia, Giancarlo Gioia ^{[1
]}

Pellei, Maura ^{[1
]}

Santini, Carlo ^{[1
]}

机构：

[1] Univ Camerino, Dept Chem Sci, I-62032 Camerino, MC, Italy

[2] Univ Padua, Dept Pharmaceut Sci, I-35131 Padua, Italy

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2008年 / 11卷 / 09期

关键词：

scorpionates; silver(I); gold(I); 1,2,4-triazole; N-heterocyclic carbenes; X-ray; spectroscopy;

D O I：

10.1016/j.inoche.2008.06.005

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis, spectroscopic and structural characterization of the carbene ligand precursor bis(4-benzyl-1,2,4-triazol-4-ium-1-yl)dihydroborate has been described. Treatment with Ag2O leads to the silver(I) complex of the new monoanionic bis(4-benzyl-1,2,4-triazol-5-ylidene-1-yl)dihydroborate dicarbene ligand. The resulting dimetallacycle carbene complex has been used to synthesize the homoleptic gold(I) complex by transmetallation reaction. (C) 2008 Elsevier B.V. All rights reserved.

引用

页码：1103 / 1106

页数：4

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