gamma-radiolysis of alkaline aqueous solutions of hexavalent plutonium

被引：0
|
作者：
Gogolev, AV
Shilov, VP
Pikaev, AK
机构：
来源：
HIGH ENERGY CHEMISTRY | 1997年 / 31卷 / 03期
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D O I：
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中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The results of the study on gamma-radiolysis of aerated alkaline aqueous solutions of Pu(VI) are presented. It was determined that G[-Pu(VI)] is equal to 1.4 ion/100 eV, irrespective of alkali concentration within the examined range (from 1.3 to 6.9 mol/l). It was found that a fine suspension and, afterwards, a precipitate of Pu(IV) hydroxide were formed. A plausible mechanism of radiolytic conversions was discussed.
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页码：155 / 158
页数：4
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