New two-dimensional Mn(II) metal-organic framework featured spin canting

被引：26
作者：
Chen, Xin [1 ]
Wang, Yao-Yu [1 ]
Liu, Bin [1 ]
Yin, Bing [1 ]
Liu, Ping [1 ]
Shi, Qi-Zhen [1 ]
机构：
[1] NW Univ Xian, Coll Chem & Mat Sci, Shaanxi Key Lab Physicoinorgan Chem, Key Lab Synthet & Nat Funct Mol Chem,Minist Educ, Xian 710069, Peoples R China
来源：
DALTON TRANSACTIONS | 2013年 / 42卷 / 19期
基金：
中国博士后科学基金; 中国国家自然科学基金;
关键词：
FERROMAGNETIC-ANTIFERROMAGNETIC INTERACTIONS; SCHIFF-BASE COMPLEXES; COORDINATION POLYMERS; CRYSTAL-STRUCTURES; 2ND-HARMONIC GENERATION; MAGNETIC BISTABILITY; DENSITY DISTRIBUTION; MOLECULAR MAGNET; NI-II; MANGANESE(II);
D O I：
10.1039/c3dt32556c
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A two-dimensional (2D) complex {[Mn-1.5(L)(bpe)(1.5)]center dot(bpe)(0.5)}(n) (1) (H3L = 3-(2-carboxy-phenoxy)phthalic acid, bpe = 1,2-bis(4-pyridyl)ethene), consisting of manganese(II) chains and bridging bpe ligands, has been synthesized and characterized. The magnetic behavior of 1 can be simulated as a -J(1)J(1)J(2)-alternating chain. Magnetic studies show that this complex magnetic behavior belongs to spin canting and exhibits an unusually high T-c around 40 K. A theoretical study based on DFT-BS calculations provides some insight into the underlying mechanism of the novel magnetic properties.
引用
收藏
页码：7092 / 7100
页数：9
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