Copper-Catalyzed Alkene Arylation with Diaryliodonium Salts

被引:183
作者
Phipps, Robert J. [1 ]
McMurray, Lindsay [1 ]
Ritter, Stefanie [1 ]
Duong, Hung A. [1 ]
Gaunt, Matthew J. [1 ]
机构
[1] Univ Cambridge, Dept Chem, Cambridge CB2 1EW, England
基金
英国工程与自然科学研究理事会; 英国生物技术与生命科学研究理事会;
关键词
ENANTIOSELECTIVE ALPHA-ARYLATION; CROSS-COUPLING REACTIONS; HECK REACTION; PALLADIUM; ARYL; OLEFINS;
D O I
10.1021/ja3039807
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Alkenes and arenes represent two classes of feedstock compounds whose union has fundamental importance to synthetic organic chemistry. We report a new approach to alkene arylation using diaryliodonium salts and Cu catalysis. Using a range of simple alkenes, we have shown that the product outcomes differ significantly from those commonly obtained by the Heck reaction. We have used these insights to develop a number of new tandem and cascade reactions that transform readily available alkenes into complex arylated products that may have broad. applications in chemical synthesis.
引用
收藏
页码:10773 / 10776
页数:4
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