Synthesis and molecular structure of bis(2-benzoylimino-benzimidazolinato)copper(II)-dimethylformamide - a metal-containing guanidine derivative

被引：12

作者：

Beyer, L

Richter, R

Wolf, R

Zaumseil, J

Lino-Pacheco, M

Angulo-Cornejo, J

机构：

[1] Univ Leipzig, Dept Inorgan Chem, D-04103 Leipzig, Germany

[2] Univ Nacl Mayor San Marcos, Fac Quim & Ingn Quim, Lima 14, Peru

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 1999年 / 2卷 / 05期

关键词：

guanidine derivative complexes; copper(II) complexes; nickel(II) complexes; acylisourea complexes; crystal structures;

D O I：

10.1016/S1387-7003(99)00043-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Bis(2-benzoylimino-benzimidazolinato)copper(II) (1) as the first neutral chelate of an acylimino-benzimidazoline contains guanidine and amide moieties directly coordinated to a metal atom. The ligands art: arranged in trans position. The synthesis of cis-bis (pyridine)bis(N-benzoyl-O-ethyl-N'-m-nitrophenyl-isoureato)nickel(II) (2) is described. The: molecular structures of both complexes were determined by X-ray crystal structure analysis. (C) 1999 Elsevier Science S.A. All rights reserved.

引用

页码：184 / 187

页数：4

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