A new Ru catalyst for alkene-alkyne coupling

被引：86

作者：

Trost, BM ^{[1
]}

Toste, FD ^{[1
]}

机构：

[1] Stanford Univ, Dept Chem, Stanford, CA 94305 USA

来源：

TETRAHEDRON LETTERS | 1999年 / 40卷 / 44期

基金：

美国国家卫生研究院; 美国国家科学基金会;

关键词：

ene type addition; ruthenium catalysis; atom economy; carbon-carbon bond formation; alkyne addition; alkene addition;

D O I：

10.1016/S0040-4039(99)01639-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[CpRu(CH3CN3)](+)PF6(-) proves to be an effective catalyst for an intermolecular Alder ene type reaction that provides considerable broadening of scope of the process. (C) 1999 Elsevier Science Ltd. All rights reserved.

引用

页码：7739 / 7743

页数：5

共 17 条

[1] Selective transformations of alkynes with ruthenium catalysts
Bruneau, C
Dixneuf, PH
[J]. CHEMICAL COMMUNICATIONS, 1997, (06) : 507 - 512
[2] PHOTOCHEMICAL PROPERTIES OF THE CYCLOPENTADIENYL(ETA-6-BENZENE)RUTHENIUM(II) CATION - THE SYNTHESIS AND REACTIONS OF A SYNTHETICALLY USEFUL INTERMEDIATE - THE CYCLOPENTADIENYLTRIS(ACETONITRILE)RUTHENIUM(II) CATION
GILL, TP
MANN, KR
[J]. ORGANOMETALLICS, 1982, 1 (03) : 485 - 488
[3] High arenophilicity and water tolerance in direct derivatization of peptides and proteins by metal π-coordination
Grotjahn, DB
Joubran, C
Combs, D
Brunet, DC
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (45) : 11814 - 11815
[4] Total synthesis of the cyclic biphenyl ether peptides K-13 and OF4949-III via SNAr macrocyclization of peptidyl ruthenium pi-arene complexes
Janetka, JW
Rich, DH
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (28) : 6488 - 6495
[5] Ruthenium-catalyzed coupling of unactivated olefins with unactivated alkynes
Murakami, M
Ubukata, M
Ito, Y
[J]. TETRAHEDRON LETTERS, 1998, 39 (40) : 7361 - 7364
[6] Application of arene-ruthenium chemistry to a formal total synthesis of OF 4949 III
Pearson, AJ
Zhang, PL
Lee, K
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1996, 61 (19) : 6581 - 6586
[7] Catalyzed cyclization of α,ω-dienes:: A versatile protocol for the synthesis of functionalized carbocyclic and heterocyclic compounds
Radetich, B
RajanBabu, TV
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (31) : 8007 - 8008
[8] A titanocene-catalyzed intramolecular ene reaction: Cycloisomerization of enynes and dienynes
Sturla, SJ
Kablaoui, NM
Buchwald, SL
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (09) : 1976 - 1977
[9] THE ATOM ECONOMY - A SEARCH FOR SYNTHETIC EFFICIENCY
TROST, BM
[J]. SCIENCE, 1991, 254 (5037) : 1471 - 1477
[10] RUTHENIUM-CATALYZED ADDITION OF ALLYL ALCOHOLS AND ACETYLENES - A SIMPLE SYNTHESIS OF GAMMA,DELTA-UNSATURATED KETONES
TROST, BM
MARTINEZ, JA
KULAWIEC, RJ
INDOLESE, AF
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (22) : 10402 - 10403

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