Catalytic enantioselective C(sp3)-H functionalization: intramolecular benzylic [1,5]-hydride shift

被引：30

作者：

Yu, Jie ^{[1
]}

Li, Nan ^{[2
]}

Chen, Dian-Feng ^{[2
]}

Luo, Shi-Wei ^{[2
]}

机构：

[1] Anhui Agr Univ, Dept Appl Chem, Hefei 230036, Peoples R China

[2] Univ Sci & Technol China, Dept Chem, Hefei 230026, Peoples R China

来源：

TETRAHEDRON LETTERS | 2014年 / 55卷 / 17期

基金：

中国博士后科学基金;

关键词：

Asymmetric catalysis; 1,5]-Hydride transfer; Benzylic C(sp(3))-H bond; Side-armed bisoxazoline; C-H BOND; CHIRAL BIS(OXAZOLINE) LIGANDS; OXAZOLINE-CONTAINING LIGANDS; RING-CLOSURE REACTIONS; ASYMMETRIC CATALYSIS; ALKYNYL ETHERS; COMPLEXES; CYCLOPROPANATION; HYDROALKYLATION; COUNTERANIONS;

D O I：

10.1016/j.tetlet.2014.03.089

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The catalytic asymmetric [1,5]-hydride transfer/cyclization sequence involving benzylic C(sp(3))-H bond was established, providing tetrahydronaphthalene derivatives in moderate to high yield with up to 69% ee, by employing the copper complex of side-armed bisoxazoline as chiral catalyst. (C) 2014 Elsevier Ltd. All rights reserved.

引用

页码：2859 / 2864

页数：6

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