Supramolecular catalytic systems based on alkylated diquaternary 1,4-diazabicyclo[2.2.2]octane derivatives

被引：7
|
作者：
Zhil'tsova, E. P. [1 ]
Gimranova, R. F. [2 ]
Lukashenko, S. S. [1 ]
Pashirova, T. N. [1 ]
Kharlampidi, Kh E. [2 ]
Zakharova, L. Ya [1 ,2 ]
机构：
[1] Russian Acad Sci, AE Arbuzov Organ & Phys Chem Inst, Kazan Sci Ctr, Kazan 420088, Tatarstan, Russia
[2] Kazan Natl Res Technol Univ, Kazan 420015, Tatarstan, Russia
来源：
KINETICS AND CATALYSIS | 2013年 / 54卷 / 05期
基金：
俄罗斯基础研究基金会;
关键词：
RIBONUCLEASE-ACTIVITY; MICELLIZATION; HYDROLYSIS; MIXTURES; BROMIDES; ACIDS;
D O I：
10.1134/S0023158413050200
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The micellization and catalytic properties of the diquaternary 1,4-diazabicyclo[2.2.2]octane derivatives, viz., 1-alkyl-4-ethyl-1,4-diazoniabicyclo[2.2.2]octane dibromides (DAD) in water were studied by conductometry, viscosimetry, and spectrophotometry. The critical micelle concentrations and the semiaxial ratio of the micellar aggregates were determined. The character and strength of the effect of the DAD micelles on the alkaline hydrolysis of 4-nitrophenyl alkylchloromethylphosphonates depend on the surfactant and substrate structures, DAD concentration in solution, and temperature. An increase in the hydrophobicity of DAD and phosphonate increases the efficiency of catalysis.
引用
收藏
页码：552 / 558
页数：7
相关论文
共 16 条
  • [1] Supramolecular catalytic systems based on 1,4-diazabicyclo[2.2.2]octane, its alkylated quaternary derivatives, and lanthanum nitrate
    Zhiltsova, E. P.
    Lukashenko, S. S.
    Pashirova, T. N.
    Zakharova, L. Ya.
    Konovalov, A. I.
    RUSSIAN CHEMICAL BULLETIN, 2015, 64 (11) : 2690 - 2696
  • [2] Supramolecular catalytic systems based on 1, 4-diazabicyclo[2.2.2]octane, its alkylated quaternary derivatives, and lanthanum nitrate
    E. P. Zhiltsova
    S. S. Lukashenko
    T. N. Pashirova
    L. Ya. Zakharova
    A. I. Konovalov
    Russian Chemical Bulletin, 2015, 64 : 2690 - 2696
  • [3] MICELLE FORMATION AND CATALYTIC ACTIVITY OF HYDROPHOBIC MONO- AND BISCATIONIC DERIVATIVES OF 1,4-DIAZABICYCLO[2.2.2] OCTANE
    Pashirova, T. N.
    Zhiltsova, E. P.
    Lukashenko, S. S.
    Zakharova, L. YA.
    LIQUID CRYSTALS AND THEIR APPLICATION, 2009, (04): : 47 - 55
  • [4] Alkylated 1,4-diazabicyclo[2.2.2]octanes: self-association, catalytic properties, and biological activity
    Zhiltsova, E. P.
    Pashirova, T. N.
    Kashapov, R. R.
    Gaisin, N. K.
    Gnezdilov, O. I.
    Lukashenko, S. S.
    Voloshina, A. D.
    Kulik, N. V.
    Zobov, V. V.
    Zakharova, L. Ya
    Konovalov, A. I.
    RUSSIAN CHEMICAL BULLETIN, 2012, 61 (01) : 113 - 120
  • [5] Alkylated 1,4-diazabicyclo[2.2.2]octanes: self-association, catalytic properties, and biological activity
    E. P. Zhiltsova
    T. N. Pashirova
    R. R. Kashapov
    N. K. Gaisin
    O. I. Gnezdilov
    S. S. Lukashenko
    A. D. Voloshina
    N. V. Kulik
    V. V. Zobov
    L. Ya. Zakharova
    A. I. Konovalov
    Russian Chemical Bulletin, 2012, 61 : 113 - 120
  • [6] Complexes of alkylated 1,4-diazabicyclo[2.2.2]octane with Ag(I) and Gd (III). Synthesis, self-association and biological activity
    Zhiltsova, Elena P.
    Islamov, Daut R.
    Gubaidullin, Aidar T.
    Lyubina, Anna P.
    Amerhanova, Syumbelya K.
    Voloshina, Alexandra D.
    Usachev, Konstantin S.
    Zakharova, Lucia Ya.
    JOURNAL OF MOLECULAR LIQUIDS, 2023, 391
  • [7] Chemical ribonucleases: 4. An analysis of the domain structure of chemical ribonucleases based on 1,4-diazabicyclo[2.2.2] octane
    Konevetz, DA
    Mironova, NL
    Beck, IE
    Zenkova, MA
    Shishkin, GV
    Vlassov, VV
    Silnikov, VN
    RUSSIAN JOURNAL OF BIOORGANIC CHEMISTRY, 2002, 28 (04) : 331 - 341
  • [8] Supramolecular systems based on 1-alkyl-4-aza-1-azoniabicyclo[2.2.2]octane bromides
    Pashirova, T. N.
    Zhil'tsova, E. P.
    Kashapov, R. R.
    Lukashenko, S. S.
    Litvinov, A. I.
    Kadirov, M. K.
    Zakharova, L. Ya.
    Konovalov, A. I.
    RUSSIAN CHEMICAL BULLETIN, 2010, 59 (09) : 1745 - 1752
  • [9] 1,4-Diazabicyclo[2.2.2]octane-Promoted Addition Reaction of Tricarbonyl Monohydrates with Active Alkynes via Consecutive C-C/C-O Cleavage
    Zhang, Jinfeng
    Ye, Ruyi
    Li, Ziyang
    Meng, Lingguo
    CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2021, 41 (11) : 4384 - 4390
  • [10] Catalytic Systems Based on the Metal Complexes of 1-Alkyl-4-Aza-1-Azoniabicyclo[2.2.2]Octane Bromides
    Zhil'tsova, E. P.
    Ibatullina, M. R.
    Lukashenko, S. S.
    Nizameev, I. R.
    Kadirov, M. K.
    Zakharova, L. Ya.
    KINETICS AND CATALYSIS, 2020, 61 (02) : 269 - 275
12