Fracture toughness of difunctional epoxy resin/thermally latent initiator system modified with polyesters

被引:28
作者
Jin, Fan-Long [2 ]
Park, Soo-Jin [1 ]
机构
[1] Inha Univ, Dept Chem, Inchon 402751, South Korea
[2] Jilin Inst Chem Technol, Dept Chem Engn, Jilin 132022, Peoples R China
关键词
Epoxy resins; Polyester; Thermal latent initiator; Thermal stabilities; Fracture toughness;
D O I
10.1016/j.jiec.2008.04.003
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Aromatic polyester was used as a modifier to improve the toughness of diglycidylether of bisphenol A (DGEBA)/thermally latent initiator system. N-Benzylquinoxalinium hexafluoroantimonate (BQH) was used as a thermally latent initiator for thermal curing, and the content of polyester was varied from 2.5 to 10 wt%. The thermal latent behaviors, thermal properties, and mechanical interfacial properties of DGEBA/polyester blends were investigated with several techniques. It was found that the BQH as a latent initiator showed the activity at a comparably narrow temperature range in the present study. The K-IC of the DGEBA/polyester blends was higher than that of the neat epoxy system and exhibited a maximum value at 5 wt% polyester. The scanning electron microscope (SEM) results showed rough and plastic deformation morphologies in the DGEBA/polyester blends.
引用
收藏
页码:564 / 567
页数:4
相关论文
共 21 条
[1]  
BAUER RS, 1979, ADV CHEM SERIES AM C, V114
[2]   AMINE-TERMINATED POLY(ARYL ETHER KETONE)-EPOXY AMINE RESIN SYSTEMS AS TOUGH HIGH-PERFORMANCE MATERIALS [J].
BENNETT, GS ;
FARRIS, RJ ;
THOMPSON, SA .
POLYMER, 1991, 32 (09) :1633-1641
[3]   Investigation of the reactivity of epoxide monomers in photoinitiated cationic polymerization [J].
Bulut, U ;
Crivello, JV .
MACROMOLECULES, 2005, 38 (09) :3584-3595
[4]  
Choi JH, 2006, J IND ENG CHEM, V12, P412
[5]  
Chung DW, 2006, J IND ENG CHEM, V12, P783
[7]   Toughened epoxy hybrid nanocomposites containing both an organophilic layered silicate filler and a compatibilized liquid rubber [J].
Fröhlich, J ;
Thomann, R ;
Mülhaupt, R .
MACROMOLECULES, 2003, 36 (19) :7205-7211
[8]  
Harani H, 1998, J APPL POLYM SCI, V70, P2603, DOI 10.1002/(SICI)1097-4628(19981226)70:13<2603::AID-APP6>3.0.CO
[9]  
2-4
[10]   Improvement in fracture behaviors of epoxy resins toughened with sulfonated poly(ether sulfone) [J].
Jin, Fan-Long ;
Park, Soo-Jin .
POLYMER DEGRADATION AND STABILITY, 2007, 92 (03) :509-514