Application of TG-DTG analysis in the study of the ammoxidised carbon materials

被引:20
|
作者
Wachowski, L [1 ]
Hofman, M [1 ]
机构
[1] Adam Mickiewicz Univ Poznan, Fac Chem, PL-60780 Poznan, Poland
关键词
ammoxidation; carbon materials; TG-DTG analysis;
D O I
10.1007/s10973-005-6987-y
中图分类号
O414.1 [热力学];
学科分类号
摘要
The effect of ammoxidation on thermal stability of carbonaceous materials characterised by degree of coalification other than that of brown coal (Konin mine, Poland) or sub-bituminous coal (Konin mine, Poland) was studied by thermogravimetric (TG-DTG) method. Analysis of TG-DTG curves has shown that coal samples ammoxidised at the higher temperature show slightly lower thermal stability. It has been established the importance of the sequence in the processes of carbonisation and ammoxidation. Both the amount of nitrogen introduced on the surface of studied carbonaceous materials and the thermal stability of nitrogen groups were affected.
引用
收藏
页码:379 / 383
页数:5
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