Oxidative Alkylation of Cyclic Benzyl Ethers with Malonates and Ketones Using Oxygen as the Terminal Oxidant

被引：59
作者：
Yoo, Woo-Jin [1 ]
Correia, Camille A. [1 ]
Zhang, Yuhua [2 ]
Li, Chao-Jun [1 ]
机构：
[1] McGill Univ, Dept Chem, Montreal, PQ H3A 2K6, Canada
[2] Tulane Univ, Dept Chem, New Orleans, LA 70118 USA
来源：
SYNLETT | 2009年 / 01期
基金：
加拿大自然科学与工程研究理事会;
关键词：
copper; indium; oxygen; cross-coupling; radical reactions; SP(3) C-H; DEHYDROGENATIVE-COUPLING CDC; CARBON BOND FORMATION; N-HYDROXYPHTHALIMIDE; MOLECULAR-OXYGEN; 1,3-DICARBONYL COMPOUNDS; TERTIARY-AMINES; SODIUM-CYANIDE; NITROGEN ATOM; ACTIVATED METHYLENE;
D O I：
10.1055/s-0028-1087376
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A simple oxidative alkylation of cyclic benzyl ethers with malonates and ketones was developed using a mixture of Cu(OTf)(2), InCl3, and NHPI as catalyst under an atmospheric pressure of oxygen.
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页码：138 / 142
页数：5
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