Hydroformylation in fluorous solvents

被引：33

作者：

Foster, DF ^{[1
]}

Adams, DJ

Gudmunsen, D

Stuart, AM

Hope, EG

Hamilton, DJ

机构：

[1] Univ St Andrews, Sch Chem, Catalyst Evaluat & Optimisat Serv, St Andrews KY16 9ST, Fife, Scotland

[2] Univ Leicester, Dept Chem, Leicester LE1 7RH, Leics, England

来源：

CHEMICAL COMMUNICATIONS | 2002年 / 07期

关键词：

D O I：

10.1039/b110061k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Triaryl-phosphines and -phosphites bearing fluorous ponytails give high rates, good linear selectivity and good retention of catalyst in the fluorous phase during hydroformylation of alkenes in fluorous solvents.

引用

页码：722 / 723

页数：2

共 11 条

[1] Phosphorus(III) ligands with fluorous ponytails [J].

Bhattacharyya, P ;

Gudmunsen, D ;

Hope, EG ;

Kemmitt, RDW ;

Paige, DR ;

Stuart, AM .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1997, (24) :3609-3612

[2]

BREWESTER EAV, 1976, Patent No. 4247486

[3]

Cornils B., 1996, APPL HOMOGENEOUS CAT

[4]

Frohling C.D., 1996, APPL HOMOGENEOUS CAT

[5] FACILE CATALYST SEPARATION WITHOUT WATER - FLUOROUS BIPHASE HYDROFORMYLATION OF OLEFINS [J].

HORVATH, IT ;

RABAI, J .

SCIENCE, 1994, 266 (5182) :72-75

[6] Molecular engineering in homogeneous catalysis:: One-phase catalysis coupled with biphase catalyst separation.: The fluorous-soluble HRh(CO){P[CH2CH2(CF2)5CF3]3}3 hydroformylation system [J].

Horváth, IT ;

Kiss, G ;

Cook, RA ;

Bond, JE ;

Stevens, PA ;

Rábai, J ;

Mozeleski, EJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (13) :3133-3143

[7] Effects of the ponytails of arylphosphines on the hydroformylation of higher olefins in supercritical CO2 [J].

Osuna, AMB ;

Chen, WP ;

Hope, EG ;

Kemmitt, RDW ;

Paige, DR ;

Stuart, AM ;

Xiao, JL ;

Xu, LJ .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2000, (22) :4052-4055

[8] Hydroformylation reactions in supercritical carbon dioxide using insoluble metal complexes [J].

Sellin, MF ;

Cole-Hamilton, DJ .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2000, (11) :1681-1683

[9] Continuous flow homogeneous catalysis: hydroformylation of alkenes in supercritical fluid-ionic liquid biphasic mixtures [J].

Sellin, MF ;

Webb, PB ;

Cole-Hamilton, DJ .

CHEMICAL COMMUNICATIONS, 2001, (08) :781-782

[10]

van Leeuwen P. W. N. M., 2000, RHODIUM CATALYSED HY

← 1 2 →