SOLVENT EXTRACTION OF STRONTIUM AND CESIUM: A REVIEW OF RECENT PROGRESS

被引：144
作者：
Xu, Chao [1 ]
Wang, Jianchen [1 ]
Chen, Jing [1 ]
机构：
[1] Tsinghua Univ, Div Nucl Chem & Chem Engn, Inst Nucl & New Energy Technol, Beijing 100084, Peoples R China
来源：
SOLVENT EXTRACTION AND ION EXCHANGE | 2012年 / 30卷 / 06期
关键词：
Solvent extraction; cesium; strontium; radioactive; fission product; high level waste; TEMPERATURE IONIC LIQUIDS; INTEGRATED AMP-PAN; CROWN-ETHER; UNEX PROCESS; HYDROGEN DICARBOLLYLCOBALTATE; FUNDAMENTAL CHEMISTRY; MOLECULAR-DYNAMICS; SIMULTANEOUS SEPARATION; SYNERGISTIC EXTRACTION; RADIATION-CHEMISTRY;
D O I：
10.1080/07366299.2012.700579
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Radioactive isotopes Cs-137 and Sr-90, two significant fission products that are usually carried into High Level Waste (HLW) during spent nuclear fuel reprocessing are suggested to be removed from HLW in order to reduce the volume of HLW and then make nuclear energy more clean and sustainable. A variety of separation techniques, including solvent extraction, have been developed for the removal of Cs-137 and Sr-90 from HLW. Among those developed separation techniques, solvent extraction is more applicable and promising, particularly for acidic HLW. This article reviews the scientific progress as well as application developments of the solvent extraction method for the separation of strontium and cesium from HLW in the last decade.
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收藏
页码：623 / 650
页数：28
相关论文
共 112 条
  • [21] Ion-exchange as a mode of cation transfer into room-temperature ionic liquids containing crown ethers: implications for the 'greenness' of ionic liquids as diluents in liquid-liquid extraction
    Dietz, ML
    Dzielawa, JA
    [J]. CHEMICAL COMMUNICATIONS, 2001, (20) : 2124 - 2125
  • [22] Extraction of strontium and cesium by dicarbollides, crown ethers and functionalized calixarenes
    Dozol, JF
    Dozol, M
    Macias, RM
    [J]. JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY, 2000, 38 (1-4) : 1 - 22
  • [23] Du Y, 2004, CHINESE CHEM LETT, V15, P1219
  • [24] Solvatochromic solvent polarity measurements of alcohol solvent modifiers and correlation with cesium extraction strength
    Duchemin, CR
    Engle, NL
    Bonnesen, PV
    Haverlock, TJ
    Delmau, LH
    Moyer, BA
    [J]. SOLVENT EXTRACTION AND ION EXCHANGE, 2001, 19 (06) : 1037 - 1058
  • [25] Synthesis and properties of calix[4]arene-bis[4-(2-ethylhexyl)benzo-crown-6], a cesium extractant with improved solubility
    Engle, NL
    Bonnesen, PV
    Tomkins, BA
    Haverlock, TJ
    Moyer, BA
    [J]. SOLVENT EXTRACTION AND ION EXCHANGE, 2004, 22 (04) : 611 - 636
  • [26] Esimantovskii V. M., 1992, Waste Management '92: Working Towards a Cleaner Environment. Waste Processing, Transportation, Storage and Disposal, Technical Programs and Public Education. Proceedings of the Symposium on Waste Management, P801
  • [27] Postoperative irradiation of pterygium with 90Sr eye applicator
    Fukushima, S
    Inoue, T
    Inoue, T
    Ozeki, S
    [J]. INTERNATIONAL JOURNAL OF RADIATION ONCOLOGY BIOLOGY PHYSICS, 1999, 43 (03): : 597 - 600
  • [28] Scale-up of caustic-side solvent extraction process for removal of cesium at Savannah River Site
    Geeting, M. W.
    Brass, E. A.
    Brown, S. J.
    Campbell, S. G.
    [J]. SEPARATION SCIENCE AND TECHNOLOGY, 2008, 43 (9-10) : 2786 - 2796
  • [29] Gemmill WJ, 1971, US Patent, Patent No. 3566124
  • [30] Glagolenko J.V., 2006, Patent No. [WO2006036083, 2006036083]
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