Instilling exploitable INHIBIT logic gate response for F-/H+ in 'end-off ' anthracene-diamine hybrid by simple functional group manipulation: Experimental study aided by DFT calculations

被引:4
作者
Bhattacharyya, Arghyadeep [1 ]
Makhal, Subhash Chandra [1 ]
Ganguly, Aniruddha [1 ]
Guchhait, Nikhil [1 ]
机构
[1] Univ Calcutta, Dept Chem, 92 APC Rd, Kolkata 700009, India
关键词
Chromogenic; Fluoride sensor; Naked eye; INHIBIT logic gate; DFT; Paper strip; FLUORIDE-ION SENSOR; NAKED-EYE DETECTION; SCHIFF-BASE; WATER; KIT;
D O I
10.1016/j.cplett.2018.02.046
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Two anthracene based receptors ADAMN and ANOPD were synthesized and characterized. The response of both towards F- ion has been monitored by UV-Vis and H-1 NMR spectroscopy as well as naked eye color change. Interestingly, change in acceptor unit endows ADAMN to behave as a INHIBIT logic gate with F- and H+ as inputs whereas ANOPD remains totally silent towards F-. The reason for this differential behavior has been explored by DFT calculations. The practical utility of the logic gate response of ADAMN was explored by successful paper strip experiment. (C) 2018 Elsevier B.V. All rights reserved.
引用
收藏
页码:106 / 111
页数:6
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