Amine-imine compounds of nickel(II) and copper(II) incorporating 1,2-ethanediamine and 1,3-propanediamine

被引：4

作者：

Curtis, Neil F. ^{[1
]}

Gladkikh, Olga P. ^{[1
]}

Robinson, Ward T. ^{[2
]}

Butcher, Raymond J. ^{[3
]}

机构：

[1] Victoria Univ Wellington, Sch Chem & Phys Sci, Box 600, Wellington 6140, New Zealand

[2] Univ Canterbury, Dept Chem, Box 8400, Christchurch 8410, New Zealand

[3] Howard Univ, Dept Chem, Washington, DC 20059 USA

来源：

INORGANICA CHIMICA ACTA | 2017年 / 457卷

关键词：

Nickel(II) compound; Copper(II) compound; Crystal structures; 2,8,8,10-Tetramethyl-3,7,11-triazatridec-2,10-diene-13-amine)nickel(II); (15-Amino-4,4,9,9,11-pentamethyl-5,8,12-triazatetradec-11-ene-2-one)copper(11); ALIPHATIC SCHIFF-BASES; TRANSITION-METAL-COMPLEXES; CARBONYL-COMPOUNDS; ION COMPLEXES; ACETONE; PERCHLORATE; DIAMINOETHANE; CRYSTAL; KETONES;

D O I：

10.1016/j.ica.2016.11.018

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction with acetone of [M(en)(tmd)](ClO4)(2) (en = 1,2-ethanediamine, tmd = 1,3-propanediamine) for M = Ni(II) forms 7RS-(2,8,8,10-tetramethy1-3,7,11-trimethyltridec-2,10-diene-13-amine)nickel(II) perchlorate with square-planar Ni(II). For M = Cu(II) the reaction forms 5RS,8RS-(15-amino-4,4,9,9,11-pentamethyl-5,8,12-tetraazapentadec-11-ene-2-one)copper(II) perchlorate 0.33 water with a N4O pentadentate ligand. The structures of these products are reported. (C) 2016 Elsevier B.V. All rights reserved.

引用

页码：90 / 94

页数：5

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