Seven-coordinate ruthenium atoms sequestered in praseodymium clusters in the chloride {RuPr3}Cl3

被引：13

作者：

Herzmann, Nina ^{[2
]}

Mudring, Ania-Verena ^{[1
]}

Meyer, Gerd ^{[2
]}

机构：

[1] Ruhr Univ Bochum, Fac Chem & Biochem, D-44780 Bochum, Germany

[2] Univ Cologne, Dept Chem Inorgan Solid State & Coordinat Chem, D-50939 Cologne, Germany

来源：

INORGANIC CHEMISTRY | 2008年 / 47卷 / 18期

关键词：

D O I：

10.1021/ic800907c

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The first example for an endohedral transition-metal atom (Ru) sequestered in a seven-coordinate surrounding of rare-earth metal atoms (Pr) has been found for {RuPr3}Cl-3. The monocapped trigonal prisms of Pr atoms share two rectangular faces, forming a zigzag chain with Ru-Ru distances of 308 pm. Intracluster bonding is dominated by Ru-Pr bonding with very little Ru-Ru bonding.

引用

页码：7954 / 7956

页数：3

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