Aluminum Monohydride Catalyzed Selective Hydroboration of Carbonyl Compounds

被引：157

作者：

Jakhar, Vineet Kumar ^{[1
]}

Barman, Milan Kr ^{[1
]}

Nembenna, Sharanappa ^{[1
]}

机构：

[1] Natl Inst Sci Educ & Res, Sch Chem Sci, Bhubaneswar 752050, Orissa, India

来源：

ORGANIC LETTERS | 2016年 / 18卷 / 18期

关键词：

ENANTIOSELECTIVE REDUCTION; HYDRIDE COMPLEXES; TRANSFER HYDROGENATION; ASYMMETRIC REDUCTION; KETONES; CATECHOLBORANE; ACTIVATION; ALDEHYDES; LIGANDS; METALS;

D O I：

10.1021/acs.orglett.6b02310

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The well-defined aluminum monohydride compound [{(2,4,6-Me-3-C6H2)NC(Me)}(2)(Me)(H)]A1H center dot(NMe2Et) (1) catalyzes hydroboration of a wide range of aldehydes and ketones under mild reaction conditions. Moreover, compound 1 displayed chemoselective hydroboration of aldehydes over ketones at rt.

引用

页码：4710 / 4713

页数：4

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