Aluminum Monohydride Catalyzed Selective Hydroboration of Carbonyl Compounds

被引：154
作者：
Jakhar, Vineet Kumar [1 ]
Barman, Milan Kr [1 ]
Nembenna, Sharanappa [1 ]
机构：
[1] Natl Inst Sci Educ & Res, Sch Chem Sci, Bhubaneswar 752050, Orissa, India
来源：
ORGANIC LETTERS | 2016年 / 18卷 / 18期
关键词：
ENANTIOSELECTIVE REDUCTION; HYDRIDE COMPLEXES; TRANSFER HYDROGENATION; ASYMMETRIC REDUCTION; KETONES; CATECHOLBORANE; ACTIVATION; ALDEHYDES; LIGANDS; METALS;
D O I：
10.1021/acs.orglett.6b02310
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The well-defined aluminum monohydride compound [{(2,4,6-Me-3-C6H2)NC(Me)}(2)(Me)(H)]A1H center dot(NMe2Et) (1) catalyzes hydroboration of a wide range of aldehydes and ketones under mild reaction conditions. Moreover, compound 1 displayed chemoselective hydroboration of aldehydes over ketones at rt.
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收藏
页码：4710 / 4713
页数：4
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