Recent Advances in the Applications of Electrochemically Generated Molybdenum and Tungsten-Based Catalysts for the Olefins Metathesis

被引：2

作者：

Karabulut, Solmaz ^{[1
,2
]}

Imamoglu, Yavuz ^{[1
,2
]}

机构：

[1] Hacettepe Univ, Dept Chem, Ankara, Turkey

[2] Hacettepe Univ, Dept Chem, TR-06800 Ankara, Turkey

来源：

SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY | 2008年 / 38卷 / 10期

关键词：

electrocatalyst; metathesis polymerization; MoCl5; olefin metathesis; WCl6;

D O I：

10.1080/15533170802525787

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Catalytic olefin metathesis has quickly emerged as one of the most often-used transformations in modern chemical synthesis. One class of catalysts that has led the way to this significant development are the electrochemically produced tungsten- and molybdenum-based species. In this review, some of the discovery, developments and applications of electrochemically generated tungsten- and molybdenum-based metathesis catalysts are outlined.

引用

页码：734 / 741

页数：8

共 78 条

[31] Gomez FJ, 1998, MACROMOL CHEM PHYS, V199, P1581
[32] Germanium-containing polymers via acyclic diene metathesis
Gómez, FJ
Wagener, KB
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1999, 592 (02) : 271 - 277
[33] Recent advances in olefin metathesis and its application in organic synthesis
Grubbs, RH
Chang, S
[J]. TETRAHEDRON, 1998, 54 (18) : 4413 - 4450
[34] Ivin K. J., 1997, OLEFIN METATHESIS ME
[35] IVIN KJ, 1982, MAKROMOL CHEM, V183, P9
[36] Electrochemically reduced tungsten-based active species as catalysts for metathesis-related reactions:: ring-opening metathesis copolymerization of cyclopentene with cyclooctene
Karabulut, S
Çetinkaya, S
Imamoglu, Y
[J]. APPLIED ORGANOMETALLIC CHEMISTRY, 2005, 19 (09) : 997 - 1001
[37] Ring-opening metathesis polymerization of cyclododecene using an electrochemically reduced tungsten-based catalyst
Karabulut, S
Çetinkaya, S
Düz, B
Imamoglu, Y
[J]. APPLIED ORGANOMETALLIC CHEMISTRY, 2004, 18 (08) : 375 - 379
[38] KARABULUT S, 2006, J MOL CATAL, V254, P186, DOI DOI 10.1016/J.MOLCATA.2005.12.046
[39] Karabulut S, 2007, NATO SCI SER II-MATH, V243, P367
[40] Metal-containing polymers synthesized via acyclic diene metathesis (ADMET) polymerization using electrochemically-reduced tungsten-based catalyst:: Polycarbosilanes
Karabulut, Solmaz
Aydogdu, Cemil
Duz, Bulent
Imamoglu, Yavuz
[J]. JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS, 2007, 17 (03) : 517 - 523

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