Bioavailability of heavy metals in water and sediments from a typical Mediterranean Bay (Malaga Bay, Region of Andalucia, Southern Spain)

被引:91
作者
Alonso Castillo, M. L. [1 ]
Sanchez Trujillo, I. [1 ]
Vereda Alonso, E. [1 ]
Garcia de Torres, A. [1 ]
Cano Pavon, J. M. [1 ]
机构
[1] Univ Malaga, Dept Analyt Chem, Fac Sci, E-29071 Malaga, Spain
关键词
Heavy metals; Sequential fractionation; Sea sediments; Sea waters; Statistical techniques; SEQUENTIAL EXTRACTION PROCEDURE; TRACE-METALS; ESTUARINE; FRACTIONATION; SPECIATION; MICROWAVE; GULF;
D O I
10.1016/j.marpolbul.2013.08.031
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Concentrations of heavy metals were measured in sediment and water from Malaga Bay (South Spain). In the later twentieth century, cities such as Malaga, have suffered the impact of mass summer tourism. The ancient industrial activities, and the actual urbanization and coastal development, recreation and tourism, wastewaters treatment facilities, have been sources of marine pollution. In sediments, Ni was the most disturbing metal because Ni concentrations exceeded the effects range low (ERL), concentration at which toxicity could start to be observed in 85% of the samples analyzed. The metal bioavailability decreased in the order: Cd > Ni > Pb > Cu > Cr. In the sea water samples, Cd and Pb were the most disturbing metals because they exceeded the continuous criteria concentration (CCC) of US EPA in a 22.5% and 10.0% of the samples, respectively. Statistical analyses (ANOVA, PCA, CA) were performed. (C) 2013 Elsevier Ltd. All rights reserved.
引用
收藏
页码:427 / 434
页数:8
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