Thermodynamic studies on thin liquid films. V. General formulation for spherical films

被引:1
作者
Iyota, Hidemi [1 ]
机构
[1] Kagoshima Prefectural Coll, Kagoshima 8900005, Japan
关键词
Spherical films; Thermodynamics and quasi-thermodynamics; Adsorption at film interfaces; Thermodynamic film thickness; Curvature dependence of film tension; Interaction between interfaces; INTERFACES; ADSORPTION; PRESSURE;
D O I
10.1007/s00396-013-2983-0
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Thermodynamic equations were derived for adsorption at interfaces of spherical films and interaction between interfaces in a film. The dependence of film tension on capillary pressure between external and film-forming phases gave thermodynamic film thickness and the one on pressure difference across the film the distance between the surface of tension for the film and the innermost dividing surface. Curvature dependence of film tension was numerically evaluated by using one of the derived equations.
引用
收藏
页码:2663 / 2679
页数:17
相关论文
共 20 条
[1]   CONTACT ANGLES IN THIN LIQUID-FILMS .2. CONTACT-ANGLE MEASUREMENTS IN NEWTON BLACK SOAP FILMS [J].
DEFEIJTER, JA ;
VRIJ, A .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1978, 64 (02) :269-277
[2]  
DEFEIJTER JA, 1988, SURFACTANT SCI SERIE, V29, pCH1
[3]   DISJOINING PRESSURE IN SOAP FILM THERMODYNAMICS [J].
ERIKSSON, JC ;
TOSHEV, BV .
COLLOIDS AND SURFACES, 1982, 5 (03) :241-264
[4]  
Exerowa D, 1997, STUDIES INTERFACE SC, P282
[5]  
GOODRICH FC, 1969, SURFACE COLLOID SCI, V1
[6]  
Guggenheim EA, 1977, THERMODYNAMICS, P55
[7]  
Israelachvili JN, 1985, INTERMOLECULAR SURFA
[8]  
IVANOV IB, 1988, SURFACTANT SCI SERIE, V29, pCH2
[9]   Thermodynamic studies on thin liquid films.: II.: Foam film stabilized by decyl methyl sulfoxide [J].
Iyota, H ;
Krustev, R ;
Müller, HJ .
COLLOID AND POLYMER SCIENCE, 2004, 282 (12) :1392-1402
[10]   Thermodynamic studies on thin liquid films.: I.: General formulation [J].
Iyota, H ;
Krustev, R ;
Müller, HJ .
COLLOID AND POLYMER SCIENCE, 2004, 282 (12) :1329-1340