Electrochemical properties of a cobalt(II) complex with sulfadiazine and 1,3-bis(pyridin-4-yl)propane

被引：3

作者：

Zhao, Ya-Yun ^{[1
]}

Zhao, Xiu-Hua ^{[1
]}

Zhang, Jie ^{[2
]}

Pan, Jian-Guo ^{[1
]}

Li, Xing ^{[1
]}

机构：

[1] Ningbo Univ, Fac Mat Sci & Chem Engn, Ningbo 315211, Zhejiang, Peoples R China

[2] Xiangtan Univ, Coll Chem, Xiangtan 411105, Hunan, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 2013年 / 69卷

基金：

中国国家自然科学基金;

关键词：

crystal structure; electrochemical properties; sulfadiazine; thermal stability; reduction of H2O2;

D O I：

10.1107/S010827011302297X

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

catena-Poly[[bis{4-[(pyrimidin-2-ylazanidyl)sulfonyl]aniline}cobalt(II)]-bis[mu-1,3-bis(pyridin-4-yl)propane]], [Co(C10H8N4O4S2)(2)(C13H14N2)](n) or [Co(L)(2)(bpp)](n), crystallizes as a one-dimensional polymeric structure which is further stabilized by intermolecular hydrogen bonding. The refined Flack parameter, -0.001 (10), indicates that the model represents the correct absolute structure. Investigation of the thermal stability shows that the complex is stable up to 543 K. The structure is of interest with respect to its electrochemical properties in the reduction reaction of H2O2 to H2O.

引用

页码：1096 / +

页数：11

共 25 条

[1] CRYSTAL-STRUCTURE OF 2-SULFANILAMIDOPYRIMIDINESILVER(I)
BAENZIGER, NC
STRUSS, AW
[J]. INORGANIC CHEMISTRY, 1976, 15 (08) : 1807 - 1809
[2] Synthesis, structure and antifungal properties of Co(II)-sulfathiazolate complexes
Bellú, S
Hure, E
Trapé, M
Trossero, C
Molina, G
Drogo, C
Williams, PAM
Atria, AM
Acevedo, JCM
Zacchino, S
Sortino, M
Campagnoli, D
Rizzotto, M
[J]. POLYHEDRON, 2005, 24 (04) : 501 - 509
[3] Different coordinative behaviour of methyl-substituted 2-pyridylsulfonamide derivatives as ligands in zinc complexes
Beloso, I
Castro, J
García-Vázquez, JA
Pérez-Lourido, P
Romero, J
Sousa, A
[J]. POLYHEDRON, 2003, 22 (08) : 1099 - 1111
[4] Bruker, 2005, SMART SAINT
[5] Direct electrochemical synthesis of cobalt(II) complexes of tosylamides:: crystal structures of [CoL2py2], [CoL2DMF2], [CoL2bipy] and [CoL2phen], L= [(4-methylphenyl)sulfonyl]-2-pyridylamid
Cabaleiro, S
Castro, J
García-Vázquez, JA
Romero, J
Sousa, A
[J]. POLYHEDRON, 2000, 19 (13) : 1607 - 1614
[6] Dickinson E, 1999, J AM CHEM SOC, V121, P613
[7] Reporting and evaluating absolute-structure and absolute-configuration determinations
Flack, HD
Bernardinelli, G
[J]. JOURNAL OF APPLIED CRYSTALLOGRAPHY, 2000, 33 : 1143 - 1148
[8] ON ENANTIOMORPH-POLARITY ESTIMATION
FLACK, HD
[J]. ACTA CRYSTALLOGRAPHICA SECTION A, 1983, 39 (NOV): : 876 - 881
[9] FOX CL, 1968, ARCH SURG-CHICAGO, V96, P184
[10] Bis[4-amino-N-(pyrimidin-2-yl)benzenesulfonamidato](2,2′-bipyridine)manganese(II)
He, Tian-Jing
Tan, Yan-Shu
Gu, Yun-Qiong
Chen, Zhen-Feng
Liang, Hong
[J]. ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2010, 66 : M684 - U857

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