A kinetic model of polymer degradation during extrusion

被引：36

作者：

Eldarov, EG ^{[1
]}

Mamedov, FV ^{[1
]}

Goldberg, VM ^{[1
]}

Zaikov, GE ^{[1
]}

机构：

[1] RUSSIAN ACAD SCI,SEMENOV INST CHEM PHYS,MOSCOW,RUSSIA

来源：

POLYMER DEGRADATION AND STABILITY | 1996年 / 51卷 / 03期

关键词：

D O I：

10.1016/0141-3910(95)00160-3

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Investigations and numerical representation of chemical transformation mechanisms occurring during polymer processing have recently become a very important problem. In this paper a model put forward to describe the interrelation of mechanical degradation and thermal oxidation phenomena during PE extrusion. This model permits determination of changes in molecular weight, the amounts of reacted oxygen and the quantities of accumulated peroxide together with the amount of the inhibitor used during extrusion. These parameters have a significant affect on the physical and mechanical properties of the polymer and make it possible to assess its lifetime in finished products under operating conditions.

引用

页码：271 / 279

页数：9

共 13 条

[1]

BELOV PS, 1985, VYSOKOMOL SOEDIN A+, V27, P2048

[2]

BOGAYEVSKAYA TA, 1981, VYSOKOMOL SOEDIN A+, V23, P181

[3]

BRIN EF, 1986, KHIM FIZ, V5, P938

[4]

DENISOV ET, 1990, CHEMISTRY, P218

[5] KINETICS OF MECHANICAL DEGRADATION IN MELTS UNDER MODEL CONDITIONS AND DURING PROCESSING OF POLYMERS - A REVIEW [J].

GOLDBERG, VM ;

ZAIKOV, GE .

POLYMER DEGRADATION AND STABILITY, 1987, 19 (03) :221-250

[6] KINETIC-MODEL OF THE MECHANISM OF HIGH-TEMPERATURE INHIBITED OXIDATION OF POLYMERS [J].

GOLDBERG, VM ;

VIDOVSKAYA, LA ;

ZAIKOV, GE .

POLYMER DEGRADATION AND STABILITY, 1988, 20 (02) :93-121

[7]

GOLDBERG VM, 1978, VYSOKOMOL SOEDIN A+, V20, P2437

[8]

GOLDBERG VM, 1988, POLYM YB, V5, P87

[9]

HAMETOVA MC, 1987, PLASTKO 87 SUMMARIES, P13

[10]

MONAKHOV.TV, 1974, VYSOKOMOL SOEDIN B, V16, P840

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