Magnetic structure and spin-flop transition in the A-site columnar-ordered quadruple perovskite TmMn3O6

被引:16
作者
Vibhakar, A. M. [1 ]
Khalyavin, D. D. [2 ]
Manuel, P. [2 ]
Zhang, L. [3 ,4 ]
Yamaura, K. [3 ,4 ]
Radaelli, P. G. [1 ]
Belik, A. A. [4 ]
Johnson, R. D. [1 ]
机构
[1] Univ Oxford, Dept Phys, Clarendon Lab, Oxford OX1 3PU, England
[2] Rutherford Appleton Lab STFC, ISIS Facil, Didcot OX11 OQX, Oxon, England
[3] Hokkaido Univ, Grad Sch Chem Sci & Engn, Kita Ku, North 10 West 8, Sapporo, Hokkaido 0600810, Japan
[4] Natl Inst Mat Sci, Res Ctr Funct Mat, Namiki 1-1, Tsukuba, Ibaraki 3050044, Japan
基金
英国工程与自然科学研究理事会;
关键词
HIGH-PRESSURE; REORIENTATION; CHARGE; MAGNETORESISTANCE; DIFFRACTION;
D O I
10.1103/PhysRevB.99.104424
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
We present the magnetic structure of TmMn3O6, solved via neutron powder diffraction. We demonstrate that long-range magnetic order develops below 74 K, and at 28 K a spin-flop transition occurs driven by f-d exchange and rare-earth single-ion anisotropy. In both magnetic phases, the magnetic structure may be described as a collinear ferrimagnet, contrary to conventional theories of magnetic order in the manganite perovskites. Instead, we show that these magnetic structures can be understood to arise due to ferro-orbital order, the A, A', and A '' site point symmetry, mm2, and the dominance of A-B exchange over both A-A and B-B exchange, which together are unique to the RMn3O6 perovskites.
引用
收藏
页数:10
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