Pertosylated pillar[5]arene: self-template assisted synthesis and supramolecular polymer formation

被引：15

作者：

Ruengsuk, Araya ^{[1
,2
]}

Khamphaijun, Korawit ^{[1
,2
]}

Pananusorn, Puttipong ^{[1
,2
]}

Docker, Andrew ^{[3
]}

Tantirungrotechai, Jonggol ^{[1
,2
]}

Sukwattanasinitt, Mongkol ^{[4
]}

Harding, David J. ^{[5
]}

Bunchuay, Thanthapatra ^{[1
,2
]}

机构：

[1] Mahidol Univ, Fac Sci, Dept Chem, Bangkok 10400, Thailand

[2] Mahidol Univ, Fac Sci, Ctr Excellence Innovat Chem PERCH CIC, Bangkok 10400, Thailand

[3] Univ Oxford, Dept Chem, Chem Res Lab, Mansfield Rd, Oxford OX1 3TA, England

[4] Chulalongkorn Univ, Fac Sci, Dept Chem, Bangkok 10330, Thailand

[5] Walailak Univ, Funct Mat & Nana Technol Ctr Excellence, Thasala 80160, Nakhon Si Thamm, Thailand

来源：

CHEMICAL COMMUNICATIONS | 2020年 / 56卷 / 62期

关键词：

HIGH-YIELD SYNTHESIS; BINDING; COMPLEXATION; GUEST; RECOGNITION; CHEMISTRY; HOSTS; CHAIN;

D O I：

10.1039/d0cc04005c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A facile synthesis of decatosylate pillar[5]arene 1 is reported in excellent yield (470%). The high yield is attributed to a selftemplate effect of the pendant tosylate arms. The X-ray crystal structure shows the formation of a linear supramolecular polymer, stabilised by intermolecular pillar[5]arene-tosylate inclusion complexes. These polymeric arrays persist in solution and form rod-like microfibril nanostructures evidenced by SEM.

引用

页码：8739 / 8742

页数：4

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