An Eco-Friendly and Efficient Synthesis of Benzoylformic Acid and Methyl Benzoylformate from Styrene

被引：0
作者：
Dai, Zhihong [1 ]
Peng, Xinhua [1 ]
Dong, Xiongzi [1 ]
Shi, Chunjie [1 ]
Rong, Yuan [1 ]
机构：
[1] Hefei Univ Technol, Sch Chem Engn, Hefei 230009, Peoples R China
来源：
ASIAN JOURNAL OF CHEMISTRY | 2012年 / 24卷 / 11期
关键词：
Styrene; HBr/H2O2; Benzoylformic acid; Methyl benzoylformate; TiO2/SO42-; ALPHA-KETO ESTERS; VICINAL TRICARBONYL COMPOUNDS; CARBONYL-COMPOUNDS; INHIBITORS; OXIDATION; BROMOKETONES; BROMINATION; DERIVATIVES; CHEMISTRY; H2O2-HBR;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The HBr/H2O2 system was found to be highly efficient and green catalytic system for the selective oxidation of styrene to benzoylformic acid in excellent yields under water as solvent. The process of etherification is simple, highly efficient and inexpensive by using TiO2/SO42- as catalyst.
引用
收藏
页码：4979 / 4985
页数：7
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