An Eco-Friendly and Efficient Synthesis of Benzoylformic Acid and Methyl Benzoylformate from Styrene

被引：0
|
作者：
Dai, Zhihong [1 ]
Peng, Xinhua [1 ]
Dong, Xiongzi [1 ]
Shi, Chunjie [1 ]
Rong, Yuan [1 ]
机构：
[1] Hefei Univ Technol, Sch Chem Engn, Hefei 230009, Peoples R China
来源：
ASIAN JOURNAL OF CHEMISTRY | 2012年 / 24卷 / 11期
关键词：
Styrene; HBr/H2O2; Benzoylformic acid; Methyl benzoylformate; TiO2/SO42-; ALPHA-KETO ESTERS; VICINAL TRICARBONYL COMPOUNDS; CARBONYL-COMPOUNDS; INHIBITORS; OXIDATION; BROMOKETONES; BROMINATION; DERIVATIVES; CHEMISTRY; H2O2-HBR;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The HBr/H2O2 system was found to be highly efficient and green catalytic system for the selective oxidation of styrene to benzoylformic acid in excellent yields under water as solvent. The process of etherification is simple, highly efficient and inexpensive by using TiO2/SO42- as catalyst.
引用
收藏
页码：4979 / 4985
页数：7
相关论文
共 50 条
  • [21] Building a Sulfonamide Library by Eco-Friendly Flow Synthesis
    Gioiello, Antimo
    Rosatelli, Emiliano
    Teofrasti, Michela
    Filipponi, Paolo
    Pellicciari, Roberto
    ACS COMBINATORIAL SCIENCE, 2013, 15 (05) : 235 - 239
  • [22] Synthesis of soluble cellulose tosylates in an eco-friendly medium
    Schmidt, S.
    Liebert, T.
    Heinze, T.
    GREEN CHEMISTRY, 2014, 16 (04) : 1941 - 1946
  • [23] Novel eco-friendly glass synthesis as corrosion inhibitors for copper in sulfuric acid medium
    Issam, Saber
    Dahmani, Khadija
    Kharbouch, Otmane
    Galai, Mouhsine
    Hsissou, Rachid
    Alobaid, Abeer A.
    Almaswari, Basheer M.
    EL-Serehy, Hamed
    Ebntouhami, Mohamed
    Elyoubi, Mohamedsalaheddine
    ANTI-CORROSION METHODS AND MATERIALS, 2025, : 320 - 330
  • [24] Phenylboronic Acid as Efficient and Eco-Friendly Catalyst for the One-Pot, Three-Component Synthesis of α-Aminophosphonates under Solvent-Free Conditions
    Tibhe, Gaurao D.
    Bedolla-Medrano, Mercedes
    Cativiela, Carlos
    Ordonez, Mario
    SYNLETT, 2012, (13) : 1931 - 1936
  • [25] Facile, Efficient Diastereoselective Synthesis of Tetrahydroquinoline Scaffolds Using Propylene Carbonate as an Eco-Friendly Solvent
    Forero, Josue S. B.
    de Carvalho, Erika M.
    Junior, Joel J.
    da Silva, Flavia M.
    CURRENT ORGANIC SYNTHESIS, 2015, 12 (01) : 102 - 107
  • [26] Facile, efficient and eco-friendly synthesis of 5-sulfenyl tetrazole derivatives of indoles and pyrroles
    Kuhn, Bruna L.
    Fortes, Margiani P.
    Kaufman, Teodoro S.
    Silveira, Claudio C.
    TETRAHEDRON LETTERS, 2014, 55 (09) : 1648 - 1652
  • [27] Eco-friendly and efficient synthesis of benzimidazole derivatives using iron oxide modified sepiolite catalyst
    Eren, B.
    Erdogan, G.
    REACTION KINETICS MECHANISMS AND CATALYSIS, 2012, 107 (02) : 333 - 344
  • [28] Highly efficient green synthesis of the photochromic spironaphthoxazines using an eco-friendly choline hydroxide catalyst
    Vajekar, Shailesh N.
    Shankarling, Ganapati S.
    SYNTHETIC COMMUNICATIONS, 2020, 50 (03) : 338 - 347
  • [29] Highly efficient and eco-friendly acid corrosion inhibitor for mild steel: Experimental and theoretical study
    Kumar, Harish
    Yadav, Vikas
    JOURNAL OF MOLECULAR LIQUIDS, 2021, 335
  • [30] An efficient and eco-friendly synthesis, computational assay and antimicrobial evaluation of some novel diastereoselective monocyclic cis-β-lactams
    Mishra, Mahesh Kumar
    Singh, Vedeshwar Narayan
    Muhammad, Shabbir
    Aloui, Zouhaier
    Sangeeta, S.
    Noorussabah, N.
    Ahmad, Khursheed
    Choudhary, Mukesh
    Sharma, Sitaram
    JOURNAL OF MOLECULAR STRUCTURE, 2020, 1219
12345