Synthesis of α-Fe2O3 dendrites by a hydrothermal approach and their application in lithium-ion batteries

被引:40
作者
Pan, Qingtao [1 ]
Huang, Kai [1 ]
Ni, Shibing [1 ]
Yang, Feng [1 ]
Lin, Shumei [1 ]
He, Deyan [1 ]
机构
[1] Lanzhou Univ, Dept Phys, Lanzhou 730000, Peoples R China
关键词
MAGNETIC-PROPERTIES; ELECTROCHEMICAL PROPERTIES; ELECTRODE MATERIALS; IRON; OXIDES; NANOPARTICLES; SPECTROSCOPY; NANOTUBES; MOSSBAUER; CELLS;
D O I
10.1088/0022-3727/42/1/015417
中图分类号
O59 [应用物理学];
学科分类号
摘要
Hematite alpha-Fe2O3 dendrites with lengths of 1-4.5 mu m along the trunk were synthesized by a low-temperature hydrothermal method. The morphology and the crystal structure of the final products were characterized. The magnetic evaluations showed that the as-prepared alpha-Fe2O3 dendrites have a high coercivity. The electrochemical performance as anode material for lithium-ion batteries was further evaluated by charge-discharge measurement. It was demonstrated that the material could provide an initial capacity of 1560 mA h g(-1), 1095 mA h g(-1) and 670 mA h g(-1) at a current density of 0.1 mA cm(-2), 0.2 mA cm(-2) and 1 mA cm(-2), respectively.
引用
收藏
页数:5
相关论文
共 22 条
  • [1] Shape and magnetic properties of single-crystalline hematite (α-Fe2O3) nanocrystals
    Cao, Huaqiang
    Wang, Guozhi
    Zhang, Lei
    Liang, Yu
    Zhang, Sichun
    Zhang, Xinrong
    [J]. CHEMPHYSCHEM, 2006, 7 (09) : 1897 - 1901
  • [2] Single-crystal dendritic micro-pines of magnetic α-Fe2O3:: Large-scale synthesis, formation mechanism, and properties
    Cao, MH
    Liu, TF
    Gao, S
    Sun, GB
    Wu, XL
    Hu, CW
    Wang, ZL
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (27) : 4197 - 4201
  • [3] α-Fe2O3 nanotubes in gas sensor and lithium-ion battery applications
    Chen, J
    Xu, LN
    Li, WY
    Gou, XL
    [J]. ADVANCED MATERIALS, 2005, 17 (05) : 582 - +
  • [4] In situ XPS analysis of various iron oxide films grown by NO2-assisted molecular-beam epitaxy
    Fujii, T
    de Groot, FMF
    Sawatzky, GA
    Voogt, FC
    Hibma, T
    Okada, K
    [J]. PHYSICAL REVIEW B, 1999, 59 (04): : 3195 - 3202
  • [5] Laser induced photo-catalytic oxidation/splitting of water over α-Fe2O3, WO3, TiO2 and NiO catalysts:: activity comparison
    Gondal, MA
    Hameed, A
    Yamani, ZH
    Suwaiyan, A
    [J]. CHEMICAL PHYSICS LETTERS, 2004, 385 (1-2) : 111 - 115
  • [6] The effect of Al addition on the gas sensing properties of Fe2O3-based sensors
    Han, JS
    Bredow, T
    Davey, DE
    Yu, AB
    Mulcahy, DE
    [J]. SENSORS AND ACTUATORS B-CHEMICAL, 2001, 75 (1-2) : 18 - 23
  • [7] Preparation, structure, and properties of three-dimensional ordered α-Fe2O3 nanoparticulate film
    Huo, LH
    Li, W
    Lu, LH
    Cui, HN
    Xi, SQ
    Wang, J
    Zhao, B
    Shen, YC
    Lu, ZH
    [J]. CHEMISTRY OF MATERIALS, 2000, 12 (03) : 790 - 794
  • [8] Hybrid nanorod-polymer solar cells
    Huynh, WU
    Dittmer, JJ
    Alivisatos, AP
    [J]. SCIENCE, 2002, 295 (5564) : 2425 - 2427
  • [9] Preparation of α-Fe2O3 electrode materials via solution process and their electrochemical properties in all-solid-state lithium batteries
    Kitaura, Hirokazu
    Takahashi, Kenji
    Mizuno, Fuminori
    Hayashi, Akitoshi
    Tadanaga, Kiyoharu
    Tatsumisago, Masahiro
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2007, 154 (07) : A725 - A729
  • [10] Combined XRD, EXAFS, and Mossbauer studies of the reduction by lithium of α-Fe2O3 with various particle sizes
    Larcher, D
    Bonnin, D
    Cortes, R
    Rivals, I
    Personnaz, L
    Tarascon, JM
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2003, 150 (12) : A1643 - A1650