Synthesis and Self-Assembly of Bolaamphiphiles Based on β-Amino Acids or an Alcohol

被引：5

作者：

Mainkar, Prathama S. ^{[1
]}

Sridhar, Chirumarry ^{[1
]}

Sudhakar, Ambadi ^{[1
]}

Chandrasekhar, Srivari ^{[1
]}

机构：

[1] Indian Inst Chem Technol, CSIR, Div Nat Prod Chem, Hyderabad 500007, Andhra Pradesh, India

来源：

HELVETICA CHIMICA ACTA | 2013年 / 96卷 / 01期

关键词：

Bolaamphiphiles; Self-assembly; Amino acids; Glycosides; AZT; Norbornenes; CARBOXYLIC-ACIDS; OLIGOMERS; 14-HELIX; GELATORS; PEPTIDE;

D O I：

10.1002/hlca.201200060

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthesis of bolaamphiphiles from unusual beta-amino acids or an alcohol and C12 or C20 spacers is described. Unusual beta-amino acids such as a sugar amino acid, an AZT-derived amino acid, a norbornene amino acid, and an AZT-derived amino alcohol were coupled with spacers under standard conditions to get the novel bolaamphiphiles 58 (Scheme 1), 12 and 13 (Scheme 2), and 17 and 20 (Scheme 3). Some of these compounds, on precipitation from MeOH/H2O, self-assembled into organized molecular structures.

引用

页码：99 / 108

页数：10

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