A Zinc(II) Coordination Polymer with Tetraiodoterephthalate: Synthesis, Crystal Structure, and Luminescence

被引：5
作者：
Chen, Le [1 ]
Chen, Sheng-Chun [1 ]
Zhang, Zhi-Hui [1 ]
Sun, Fu-An [1 ]
Cui, Ai-Jun [1 ]
Gao, Hai-Bo [2 ]
He, Ming-Yang [1 ]
Chen, Qun [1 ]
机构：
[1] Changzhou Univ, Key Lab Fine Petrochem Technol, Changzhou 213164, Peoples R China
[2] Linyi Univ, Coll Life Sci, Linyi 276002, Peoples R China
来源：
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 2012年 / 67卷 / 08期
关键词：
Coordination Polymer; Zn(II) Tetraiodoterephthalate; Crystal Structure; Luminescence; METAL-ORGANIC FRAMEWORKS; ARCHITECTURES; COMPLEXES; DESIGN; LIGAND; 1D;
D O I：
10.5560/ZNB.2012-0140
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new coordination polymer {[Zn(BDC-I-4)(DMSO)(2)]center dot(DMSO)(2)(H2O)(4)}(n) (1) was prepared from the reaction of Zn(II) nitrate with 2,3,5,6-tetraiodo-1,4-benzenedicarboxylic acid (H2BDC-I-4) in DMSO/water and characterized by elemental analysis, IR spectroscopy and single-crystal X-ray diffraction. Complex 1 crystallizes in the orthorhombic space group Puma and shows a zigzag chain coordination structure, which is assembled into a 2D network through weak C-H center dot center dot center dot O and C-H center dot center dot center dot pi interactions. The thermal and photoluminescence properties of complex 1 in the solid state are also reported.
引用
收藏
页码：843 / 848
页数：6
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