Inverse opal tungsten trioxide films with mesoporous skeletons: synthesis and photoelectrochemical responses

被引:34
作者
Kim, Jung Kyu [1 ,2 ]
Moon, Jun Hyuk [3 ]
Lee, Tae-Woo [4 ]
Park, Jong Hyeok [1 ,2 ]
机构
[1] Sungkyunkwan Univ, SKKU Adv Inst Nano technol, Suwon 440746, South Korea
[2] Sungkyunkwan Univ, Sch Chem Engn, Suwon 440746, South Korea
[3] Sogang Univ, Dept Chem & Biomol Engn, Seoul 121742, South Korea
[4] Pohang Univ Sci & Technol POSTECH, Dept Mat Sci & Engn, Gyungbuk 790784, South Korea
关键词
PHOTOCATALYTIC DEGRADATION; WATER; PHOTOANODES; DYES;
D O I
10.1039/c2cc36984b
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Inverse opal structured tungsten trioxide (WO3) films with mesoporous morphology were prepared using self-assembled polystyrene (PS) colloid as an organic template and by addition of polyethyleneglycol (PEG) to a precursor as an organic surfactant. The photoelectrochemical properties of these films were investigated. By adjusting the tungsten to PEG weight ratio in the precursor, an inverse opaline WO3 film with a nano-particular skeleton and increased specific surface area was constructed. The unique morphology of this film led to enhanced photoelectrochemical catalytic responses under UV-Visible 1-sun illumination.
引用
收藏
页码:11939 / 11941
页数:3
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