Relative humidity control in polymer electrolyte membrane fuel cells without extra humidification

被引:35
作者
Riascos, Luis A. M. [1 ]
机构
[1] Fed Univ ABC, BR-09210170 Santo Andre, SP, Brazil
基金
巴西圣保罗研究基金会;
关键词
polymer electrolyte membrane fuel cells; relative humidity control;
D O I
10.1016/j.jpowsour.2008.06.032
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The performance of polymer electrolyte membrane fuel cells is highly influenced by the water content in the membrane. To prevent the membrane from drying, several researchers have proposed extra humidification on the input reactants. But in some applications, the extra size and weight of the humidifier should be avoided. In this research a control technique, which maintains the relative humidity on saturated conditions, is implemented by adjusting the air stoichiometry; the effects of drying of membrane and flooding of electrodes are considered, as well. For initial analysis, a mathematical model reveals the relationship among variables that can be difficult to monitor in a real machine. Also prediction can be tested optimizing time and resources. For instance, the effects of temperature and humidity can be analyzed separately. For experimental validation, tests in a fault tolerant fuel cell are conducted. (C) 2008 Elsevier B.V. All rights reserved.
引用
收藏
页码:204 / 211
页数:8
相关论文
共 26 条
[21]   PEMFC in situ liquid-water-content monitoring status [J].
St-Pierre, Jean .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2007, 154 (07) :B724-B731
[22]   PtTiOx/OC electrocatalysts with improved durability in H2/O2 PEMFCs without external humidification [J].
Tian, Juan ;
Sun, Gongquan ;
Cai, Mei ;
Mao, Qing ;
Xin, Qin .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2008, 155 (02) :B187-B193
[23]   Measurement of flooding in gas diffusion layers of polymer electrolyte fuel cells with conventional flow field [J].
Yamada, Haruhiko ;
Hatanaka, Tatsuya ;
Murata, Hajime ;
Morimoto, Yu .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2006, 153 (09) :A1748-A1754
[24]   Steady state and dynamic performance of proton exchange membrane fuel cells (PEMFCs) under various operating conditions and load changes [J].
Yan, Qiangu ;
Toghiani, H. ;
Causey, Heath .
JOURNAL OF POWER SOURCES, 2006, 161 (01) :492-502
[25]   Transient behavior of a proton exchange membrane fuel cell under dry operation [J].
Yu, HM ;
Ziegler, C .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2006, 153 (03) :A570-A575
[26]   Effects of porosity distribution variation on the liquid water flux through gas diffusion layers of PEM fuel cells [J].
Zhan, Zhigang ;
Xiao, Jinsheng ;
Li, Dayong ;
Pan, Mu ;
Yuan, Runzhang .
JOURNAL OF POWER SOURCES, 2006, 160 (02) :1041-1048