OCTAFLUORO[2.2]PARACYCLOPHANE (AF4) QUINONE

被引：0

作者：

Xu, Wei ^{[1
]}

Dolbier, William R., Jr. ^{[1
]}

Duan, Jian-Xin ^{[1
]}

Zhai, Yian ^{[1
]}

Ogawa, Katsu ^{[1
]}

Battiste, Merle A. ^{[1
]}

Ghiviriga, Ion ^{[1
]}

机构：

[1] Univ Florida, Dept Chem, Gainesville, FL 32611 USA

来源：

COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS | 2008年 / 73卷 / 12期

基金：

美国国家科学基金会;

关键词：

Cyclophane; Fluorinated compounds; Oxidations; 2.2]Paracyclophane; Quinones; Cyclic voltammetry; UV spectra; Diels-Alder reaction;

D O I：

10.1135/cccc20081764

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Octafluoro[2.2]paracyclophane (AF4) has been oxidized by treatment with HIO3 in CF3CO2H to form the corresponding p-quinone along with a unique triketone. This quinone undergoes reduction to the respective hydroquinone as well as a Diels-Alder reaction with 1,3-cyclohexadiene. Its reduction potential was obtained by cyclic voltammetry and is discussed in the context of other quinones.

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页码：1764 / 1776

页数：13

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