Thin piezoelectric films with thickness around 100nm are critical for high frequency bulk acoustic resonators and filters, especially in mm-wave frequency range. In this work, 100nm and 50nm 30% Sc doped AlN (Al0.7Sc0.3N) films have been deposited and the high-tone bulk acoustic wave resonators (HBAR) have been fabricated to characterize the thin piezoelectric films. The intrinsic electromechanical coupling coefficient (K-t(2)) of the sub-100nm Al0.7Sc0.3N thin films has been extracted by measurements and modeling of the fabricated HBAR devices. The coupling coefficient of the deposited 100nm and 50nm Al0.7Sc0.3N thin films is 7.9% and 5.6% respectively. These results show that the sub-100nm Sc doped AIN films are promising for the nextgeneration acoustic resonators and filters for mm-wave applications.