Successful oxidation of Ph2P(CH2)nPPh2 (n=2, 4, 6) by tellurium leading to Ph2P(Te)(CH2) nP(Te)Ph2

被引:7
作者
Jeremias, Lukas [1 ]
Babiak, Michal [1 ]
Kubat, Vaclav [1 ]
Calhorda, Maria Jose [2 ]
Travnicek, Zdenek [3 ]
Novosad, Josef [1 ,3 ]
机构
[1] Masaryk Univ, Fac Sci, Dept Chem, CZ-61137 Brno, Czech Republic
[2] Univ Lisbon, Fac Ciencias, CQB, Dept Quim & Bioquim, PT-1749016 Lisbon, Portugal
[3] Palacky Univ, Fac Sci, Dept Inorgan Chem, CZ-77146 Olomouc, Czech Republic
关键词
COMPLEXES; LIGANDS; HG;
D O I
10.1039/c4ra00157e
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The first successful syntheses of Ph2P(Te)(CH2) P-n(Te) Ph-2 ( n 2, 4, 6) via oxidation of Ph2P(CH2) nPPh2 by telluriumpowder are reported. The prepared compounds were characterized by elemental analysis, P-31 and Te-125 NMR spectroscopy, and single- crystal X-ray analysis.
引用
收藏
页码:15428 / 15430
页数:3
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