Influence of Chemical Effect on the Kβ/Kα Intensity Ratios and Kβ Energy Shift of Co, Ni, Cu, and Zn Complexes

被引：9

作者：

Apaydin, G. ^{[1
]}

Aylikci, V. ^{[1
]}

Biyiklioglu, Z. ^{[2
]}

Tirasoglu, E. ^{[1
]}

Kantekin, H. ^{[2
]}

机构：

[1] Karadeniz Tech Univ, Dept Phys, Fac Arts & Sci, TR-61080 Trabzon, Turkey

[2] Karadeniz Tech Univ, Dept Chem, Fac Arts & Sci, TR-61080 Trabzon, Turkey

来源：

CHINESE JOURNAL OF CHEMICAL PHYSICS | 2008年 / 21卷 / 06期

关键词：

Chemical effect; K intensity ratio; Delta E energy difference; Ultra-LEGe detector; Am-241 annular radioactive source;

D O I：

10.1088/1674-0068/21/06/591-595

中图分类号：

O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];

学科分类号：

070203 ; 070304 ; 081704 ; 1406 ;

摘要：

Chemical effects on the K-beta/K-alpha intensity ratios and Delta E energy differences for Co, Ni, Cu, and Zn complexes were investigated. The samples were excited by 59.5 keV gamma-rays from a Am-241 annular radioactive source. K X-rays emitted by samples were counted by an Ultra-LEGe detector with a resolution of 150 eV at 5.9 keV. We observed the effects of different ligands on the K-beta/K-alpha intensity ratios and Delta E energy differences for Co, Ni, Cu, and Zn complexes. We tried to investigate chemical effects on central atoms using the behaviors of different ligands in these complexes. The experimental values of K-beta/K-alpha were compared with the theoretical and other experimental values of pure Co, Ni, Cn, and Zn.

引用

页码：591 / 595

页数：5

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