Synthesis of chiral ferrocenylazines. Negishi cross-coupling or S N H reactions?

被引：9

作者：

Musikhina, A. A. ^{[1
,2
]}

Utepova, I. A. ^{[1
,2
]}

Serebrennikova, P. O. ^{[1
,2
]}

Chupakhin, O. N. ^{[1
,2
]}

Charushin, V. N. ^{[1
,2
]}

机构：

[1] Ural Fed Univ, Ekaterinburg 620002, Russia

[2] Russian Acad Sci, Inst Organ Synth, Ural Branch, Ekaterinburg, Russia

来源：

RUSSIAN JOURNAL OF ORGANIC CHEMISTRY | 2013年 / 49卷 / 08期

基金：

俄罗斯基础研究基金会;

关键词：

ALLYLIC SUBSTITUTION-REACTIONS; ASYMMETRIC CATALYSIS; NUCLEOPHILIC-SUBSTITUTION; LIGANDS; FERROCENYLLITHIUM; CYCLOADDITION; HYDROGENATION; HYDROBORATION; COMPLEXES; CHEMISTRY;

D O I：

10.1134/S1070428013080150

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Preparation of new hetaryl-containing planar chiral ferrocene by a nucleophilic substitution of hydrogen in azines was performed using a lithium derivative of (S)-ferrocenyl-p-tolylsulfoxide as s nucleophilic reagent.

引用

页码：1191 / 1194

页数：4

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