Improvement of (La0.74Bi0.10Sr0.16)MnO3-Bi1.4Er0.6O3 composite cathodes for intermediate-temperature solid oxide fuel cells

被引：10

作者：

Li, Junliang ^{[1
]}

Wang, Shaorong ^{[1
]}

Sun, Xiufu ^{[1
]}

Liu, Renzhu ^{[1
]}

Ye, Xiaofeng ^{[1
]}

Wen, Zhaoyin ^{[1
]}

机构：

[1] Chinese Acad Sci, Shanghai Inst Ceram, Shanghai 200050, Peoples R China

来源：

JOURNAL OF POWER SOURCES | 2008年 / 185卷 / 02期

关键词：

Intermediate-temperature solid oxide fuel cells; Cathode stability; Impedance spectroscopy; Composite cathode;

D O I：

10.1016/j.jpowsour.2008.09.012

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Porous composite cathodes including (La0.74Bi0.10Sr0.16)MnO3-delta (LBSM) and Bi1.4Er0.6O3 (ESB) were fabricated and characterized using AC impedance spectroscopy. In our earlier work, the growth and aggregation of ESB particles were found in LBSM-ESB composite cathodes. In this study, therefore, two approaches were used to restrain the growth and aggregation of ESB particles. First, the sintering temperature of the composite cathode was reduced by introducing a sintering function layer, which caused a 22% reduction in the initial polarization resistance (R), but the cathode polarization resistance decreased at a rate of 2.15 x 10-4 Omega cm(2) h(-1) at 700 degrees C during a period of 100 h. Second, nano-sized Gd-doped ceria powder (CGO) was added to the composite cathode system. Stability improvement was achieved at 10 vol% CGO, and the degradation rate at 700 degrees C was 4.01 x 10(-5) Omega cm(2) h(-1) during a period of 100 h. (C) 2008 Elsevier B.V. All rights reserved.

引用

页码：649 / 655

页数：7

共 25 条

[11] Direct current bias studies on (Bi2O3)0.8(Er2O3)0.2 electrolyte and Ag-(Bi2O3)0.8(Er2O3)0.2 cermet electrode [J].

Jaiswal, A ;

Wachsman, ED .

SOLID STATE IONICS, 2006, 177 (7-8) :677-685

[12] Bismuth-ruthenate-based cathodes for IT-SOFCs [J].

Jaiswal, A ;

Wachsman, ED .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2005, 152 (04) :A787-A790

[13] Effect of sintering temperature on microstructure and performance of LSM-YSZ composite cathodes [J].

Jorgensen, MJ ;

Primdahl, S ;

Bagger, C ;

Mogensen, M .

SOLID STATE IONICS, 2001, 139 (1-2) :1-11

[14] Performance evaluation of anode-supported solid oxide fuel cells with thin film YSZ electrolyte [J].

Leng, YJ ;

Chan, SH ;

Khor, KA ;

Jiang, SP .

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2004, 29 (10) :1025-1033

[15] (La0.74Bi0.10Sr0.16)MnO3-δ-(Bi2O3)0.7(Er2O3)0.3 composite cathodes for intermediate temperature solid oxide fuel cells [J].

Li, Junliang ;

Wang, Shaorong ;

Wang, Zhengrong ;

Liu, Renzhu ;

Wen, Tinglian ;

Wen, Zhaoyin .

JOURNAL OF POWER SOURCES, 2008, 179 (02) :474-480

[16] Electrochemical performance of (Ba0.5Sr0.5)0.9Sm0.1Co0.8Fe0.2O3-δ as an intermediate temperature solid oxide fuel cell cathode [J].

Li, Shuyan ;

Lu, Zhe ;

Ai, Na ;

Chen, Kongfa ;

Su, Wenhui .

JOURNAL OF POWER SOURCES, 2007, 165 (01) :97-101

[17] CERAMIC FUEL-CELLS [J].

MINH, NQ .

JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1993, 76 (03) :563-588

[18] Kinetic and geometric aspects of solid oxide fuel cell electrodes [J].

Mogensen, M ;

Skaarup, S .

SOLID STATE IONICS, 1996, 86-8 :1151-1160

[19] Pt-perovskite cermet cathode for reduced-temperature SOM [J].

Sasaki, K ;

Tamura, J ;

Hosoda, H ;

Lan, TN ;

Yasumoto, K ;

Dokiya, M .

SOLID STATE IONICS, 2002, 148 (3-4) :551-555

[20] Appraisal of Ce1-yGdyO2-y/2 electrolytes for IT-SOFC operation at 500°C [J].

Steele, BCH .

SOLID STATE IONICS, 2000, 129 (1-4) :95-110

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