Improvement of (La0.74Bi0.10Sr0.16)MnO3-Bi1.4Er0.6O3 composite cathodes for intermediate-temperature solid oxide fuel cells

被引：10

作者：

Li, Junliang ^{[1
]}

Wang, Shaorong ^{[1
]}

Sun, Xiufu ^{[1
]}

Liu, Renzhu ^{[1
]}

Ye, Xiaofeng ^{[1
]}

Wen, Zhaoyin ^{[1
]}

机构：

[1] Chinese Acad Sci, Shanghai Inst Ceram, Shanghai 200050, Peoples R China

来源：

JOURNAL OF POWER SOURCES | 2008年 / 185卷 / 02期

关键词：

Intermediate-temperature solid oxide fuel cells; Cathode stability; Impedance spectroscopy; Composite cathode;

D O I：

10.1016/j.jpowsour.2008.09.012

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Porous composite cathodes including (La0.74Bi0.10Sr0.16)MnO3-delta (LBSM) and Bi1.4Er0.6O3 (ESB) were fabricated and characterized using AC impedance spectroscopy. In our earlier work, the growth and aggregation of ESB particles were found in LBSM-ESB composite cathodes. In this study, therefore, two approaches were used to restrain the growth and aggregation of ESB particles. First, the sintering temperature of the composite cathode was reduced by introducing a sintering function layer, which caused a 22% reduction in the initial polarization resistance (R), but the cathode polarization resistance decreased at a rate of 2.15 x 10-4 Omega cm(2) h(-1) at 700 degrees C during a period of 100 h. Second, nano-sized Gd-doped ceria powder (CGO) was added to the composite cathode system. Stability improvement was achieved at 10 vol% CGO, and the degradation rate at 700 degrees C was 4.01 x 10(-5) Omega cm(2) h(-1) during a period of 100 h. (C) 2008 Elsevier B.V. All rights reserved.

引用

页码：649 / 655

页数：7

共 25 条

[1] Recent advances in materials for fuel cells [J].

Brandon, NP ;

Skinner, S ;

Steele, BCH .

ANNUAL REVIEW OF MATERIALS RESEARCH, 2003, 33 :183-213

[2] Silver-bismuth oxide cathodes for IT-SOFCs; Part I - Microstructural instability [J].

Camaratta, Matthew ;

Wachsman, Eric .

SOLID STATE IONICS, 2007, 178 (19-20) :1242-1247

[3] Energy and exergy analysis of simple solid-oxide fuel-cell power systems [J].

Chan, SH ;

Low, CF ;

Ding, OL .

JOURNAL OF POWER SOURCES, 2002, 103 (02) :188-200

[4] Applicability of Bi2Ru2O7 pyrochlore electrodes for ESB and BIMEVOX electrolytes [J].

Esposito, Vincenzo ;

Luong, Bac H. ;

Di Bartolomeo, Elisabetta ;

Wachsman, Eric D. ;

Traversa, Enrico .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2006, 153 (12) :A2232-A2238

[5] Perovskite cathodes for solid oxide fuel cells based on ceria electrolytes [J].

Godickemeier, M ;

Sasaki, K ;

Gauckler, LJ ;

Riess, I .

SOLID STATE IONICS, 1996, 86-8 :691-701

[6]

HEUVELN FH, 1997, J ELECTROCHEM SOC, V144, P134

[7] Imaging of oxygen transport at SOFC cathode/electrolyte interfaces by a novel technique [J].

Horita, T ;

Yamaji, K ;

Sakai, N ;

Xiong, XP ;

Kato, T ;

Yokokawa, H ;

Kawada, T .

JOURNAL OF POWER SOURCES, 2002, 106 (1-2) :224-230

[8] Oxygen reduction mechanism at porous La1-xSrxCoO3-d cathodes/La0.8Sr0.2Ga0.8Mg0.2O2.8 electrolyte interface for solid oxide fuel cells [J].

Horita, T ;

Yamaji, K ;

Sakai, N ;

Yokokawa, H ;

Weber, A ;

Ivers-Tiffée, E .

ELECTROCHIMICA ACTA, 2001, 46 (12) :1837-1845

[9] Silver-BaCe0.8Gd0.2O3 composites as cathode materials for SOFCs using BaCeO3-based electrolytes [J].

Hu, HX ;

Liu, ML .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1996, 143 (03) :859-864

[10] DOPED PRMNO3 PEROVSKITE OXIDE AS A NEW CATHODE OF SOLID OXIDE FUEL-CELLS FOR LOW-TEMPERATURE OPERATION [J].

ISHIHARA, T ;

KUDO, T ;

MATSUDA, H ;

TAKITA, Y .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1995, 142 (05) :1519-1524

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