Selective hydrogenation of 2-hydroxymethyl-5-furfural to 2,5-bis(hydroxymethyl)furan over gold sub-nano clusters

被引：143

作者：

Ohyama, Junya ^{[1
,2
]}

Esaki, Akihiko ^{[1
]}

Yamamoto, Yuta ^{[3
]}

Arai, Shigeo ^{[3
]}

Satsuma, Atsushi ^{[1
,2
]}

机构：

[1] Nagoya Univ, Grad Sch Engn, Nagoya, Aichi 4648603, Japan

[2] Kyoto Univ, ESICB, Kyoto 6158520, Japan

[3] Nagoya Univ, Ecotopia Sci Inst, Nagoya, Aichi 4648603, Japan

来源：

RSC ADVANCES | 2013年 / 3卷 / 04期

关键词：

CATALYSTS; BIOMASS; NANOPARTICLES; FUELS; SIZE; CROTONALDEHYDE; CINNAMALDEHYDE; SUPPORT; SITES; PD;

D O I：

10.1039/c2ra22190j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We report a gold sub-nano cluster supported on Al2O3 catalyzed hydrogenation of 2-hydroxymethyl-5-furfural without furan ring hydrogenation and its opening reaction, which resulted in excellent conversion to 2,5-bis(hydroxymethyl)furan (>96% yield), Fig. 1(a).

引用

收藏

页码：1033 / 1036

页数：4

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